{"id":1127,"date":"2021-01-15T21:50:36","date_gmt":"2021-01-15T19:50:36","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=1127"},"modified":"2021-03-23T11:53:46","modified_gmt":"2021-03-23T09:53:46","slug":"%d0%be%d1%87%d0%b8%d1%89%d0%b5%d0%bd%d0%bd%d1%8f-%d0%b2%d1%83%d0%b3%d0%bb%d0%b5%d0%b2%d0%be%d0%b4%d0%bd%d0%b5%d0%b2%d0%b8%d1%85-%d1%81%d1%83%d0%bc%d1%96%d1%88%d0%b5%d0%b9-%d0%b7%d0%b0-%d0%b4%d0%be","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=1127","title":{"rendered":"\u041e\u0447\u0438\u0449\u0435\u043d\u043d\u044f \u0432\u0443\u0433\u043b\u0435\u0432\u043e\u0434\u043d\u0435\u0432\u0438\u0445 \u0441\u0443\u043c\u0456\u0448\u0435\u0439 \u0437\u0430 \u0434\u043e\u043f\u043e\u043c\u043e\u0433\u043e\u044e \u0433\u0440\u0430\u043d\u0443\u043b\u044c\u043e\u0432\u0430\u043d\u0438\u0445 \u0441\u043e\u0440\u0431\u0446\u0456\u0439\u043d\u0438\u0445 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0456\u0432"},"content":{"rendered":"

\u041e\u0427\u0418\u0429\u0415\u041d\u041d\u042f \u0412\u0423\u0413\u041b\u0415\u0412\u041e\u0414\u041d\u0415\u0412\u0418\u0425 \u0421\u0423\u041c\u0406\u0428\u0415\u0419 \u0417\u0410 \u0414\u041e\u041f\u041e\u041c\u041e\u0413\u041e\u042e \u0413\u0420\u0410\u041d\u0423\u041b\u042c\u041e\u0412\u0410\u041d\u0418\u0425 \u0421\u041e\u0420\u0411\u0426\u0406\u0419\u041d\u0418\u0425 \u041c\u0410\u0422\u0415\u0420\u0406\u0410\u041b\u0406\u0412<\/p>\n

PURIFICATION OF HIDROCARBON MIXTURES BY MEANS OF GRANULAR SORPTION MATERIALS<\/p>\n

<\/a> \u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 63-70. \u041d\u043e\u043c\u0435\u0440: \u21161, 2020 (281)<\/strong>
\n\u0410\u0432\u0442\u043e\u0440\u0438:<\/strong>
\n\u0410.\u042f. \u0413\u0410\u041d\u0417\u042e\u041a
\n\u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442
\nA.Y. HANZIUK
\nKhmelnytsky National University
\nDOI:<\/strong> https:\/\/www.doi.org\/10.31891\/2307-5732-2020-281-1-63-70<\/a>
\n\u0420\u0435\u0446\u0435\u043d\u0437\u0456\u044f\/Peer review :<\/strong> 14. 01.2020 \u0440.
\n\u041d\u0430\u0434\u0440\u0443\u043a\u043e\u0432\u0430\u043d\u0430\/Printed :<\/strong> 14.02.2020 \u0440.<\/p>\n

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\n\u041a\u043b\u044e\u0447\u043e\u0432\u0456 \u0441\u043b\u043e\u0432\u0430<\/strong>: \u0433\u043b\u0438\u043d\u0438\u0441\u0442\u0438\u0439 \u043c\u0456\u043d\u0435\u0440\u0430\u043b, \u043a\u0438\u0441\u043b\u043e\u0442\u043d\u0430 \u0430\u043a\u0442\u0438\u0432\u0430\u0446\u0456\u044f, \u0433\u0440\u0430\u043d\u0443\u043b\u044f\u0442, \u0432\u0443\u0433\u043b\u0435\u0432\u043e\u0434\u043d\u0435\u0432\u0430 \u0441\u0443\u043c\u0456\u0448, \u043e\u043a\u0442\u0430\u043d\u043e\u0432\u0435 \u0447\u0438\u0441\u043b\u043e.<\/p>\n

\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n

Their drawback can be explained by the high cost and regeneration complexity. That is why the usage of natural sorbents (Tashkiv saponite deposits, Khmelnytskyi region). They are able to clean contaminated water from colloidal, molecular and ionic substances. Exploring the specified topic, physicochemical properties of various forms of saponites are studied; the area of their usage is defined. The paste for cleaning contaminated surfaces is developed on their basis. The research results have shown that the most effective method is to use natural saponite. The author of the article advises to conduct preliminary acid activation of clay minerals and modification of its surface multivalent metal salts. Saponite clay\u00a0 granulate is\u00a0 obtained\u00a0 with different time and sintering temperature. Granulation is shown to improve the strength and filtration characteristics of natural sorbents, increasing the filtration rate and the duration of the filter cycle. The influence of the granulation process on the sorption properties of the obtained granulated aluminosilicates is investigated. A detailed hydrocarbon analysis of the A-92 starting gasoline is carried out. The composition of the purified samples of the hydrocarbon mixture is evaluated with gas chromatography using saponite granulate (Octane rating = 94,013 according to the method of research) under static\u00a0 conditions. The structure changes of raw and acid activated saponite clay has been investigated by nitrogen adsorption method and scanning electron microscopy. Established that the porous structure of saponite clay mineral represented by micro-meso porous system with domination of micropores. Acid modification promotes the development of specific surface area (from 47,7 m2<\/sup>\/g to 177,9 m2<\/sup>\/g) and increase the total volume of pores (from 0,134 cm3<\/sup>\/g to 0,201 cm3<\/sup>\/g).
\nKeywords: <\/strong>clay mineral, acid activation, granulate, hydrocarbon mixture, octane number.<\/p>\n

References<\/strong><\/p>\n

    \n
  1. Sokol H. Structural, Mineral and elemental composition features of iron-rich saponite clay from Tashkiv deposit (Ukraine) \/ H. Sokol, M. Sprynskyy, A. Ganzyuk \/\/ Colloids and Interfaces. \u2013 2019. \u2013 \u2116 3. \u2013 R. 10.<\/li>\n
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  10. Sokol H. M. Ochyshchennia naftoproduktiv ta vyluchennia yikh slidovykh kilkostei z pozhezhnoho smittia za dopomohoiu sorbtsiinykh materialiv dlia podalshoho doslidzhennia khromatohrafichnym metodom \/ H. M. Sokol, A. Ya. Hanziuk, O. P. Shelestiuk, O. M. Mishchuk \/\/ Herald of Khmelnytskyi National University. \u2013 2017. \u2013 \u2116 1. \u2013 S. 87\u201394.<\/li>\n
  11. Ekspluatatsiini materialy : metodychni vkazivky do laboratornykh zaniat dlia studentiv napriamu 6.070106 \u00abAvtomobilnyi transport\u00bb dennoi formy navchannia \/ [uklad. T. V. Furs, O. Ye. Skolozdra]. \u2013 Lutsk : Lutskyi NTU, 2014. \u2013 80 s.<\/li>\n
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  13. Hanziuk A. Ya. Doslidzhennia protsesiv ochyshchennia naftoproduktiv za dopomohoiu aktyvovanykh smektytovykh hlyn \/ A. Ya. Hanziuk, D. M. Vyshnevska, N. L. Pokhylo \/\/ Herald of Khmelnytskyi National University. \u2013 2019. \u2013 \u2116 1. \u2013 S. 82\u201390.<\/li>\n
  14. Sokol H. M. Strukturna modyfikatsiia saponitovykh hlyn kyslotnoiu obrobkoiu \/ H. M. Sokol \/\/ Naukovi notatky : mizhvuzivskyi zbirnyk naukovykh prats \/ Lutskyi natsionalnyi tekhnichnyi universytet. \u2013 Lutsk, 2017. \u2013 \u2116 56. \u2013 S. 149\u2013153.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

    \u041e\u0427\u0418\u0429\u0415\u041d\u041d\u042f \u0412\u0423\u0413\u041b\u0415\u0412\u041e\u0414\u041d\u0415\u0412\u0418\u0425 \u0421\u0423\u041c\u0406\u0428\u0415\u0419 \u0417\u0410 \u0414\u041e\u041f\u041e\u041c\u041e\u0413\u041e\u042e \u0413\u0420\u0410\u041d\u0423\u041b\u042c\u041e\u0412\u0410\u041d\u0418\u0425 \u0421\u041e\u0420\u0411\u0426\u0406\u0419\u041d\u0418\u0425 \u041c\u0410\u0422\u0415\u0420\u0406\u0410\u041b\u0406\u0412 PURIFICATION OF HIDROCARBON MIXTURES BY MEANS OF GRANULAR SORPTION MATERIALS \u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 63-70. \u041d\u043e\u043c\u0435\u0440: \u21161, 2020 (281) \u0410\u0432\u0442\u043e\u0440\u0438: \u0410.\u042f. \u0413\u0410\u041d\u0417\u042e\u041a \u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442 A.Y. HANZIUK Khmelnytsky National University DOI: https:\/\/www.doi.org\/10.31891\/2307-5732-2020-281-1-63-70 \u0420\u0435\u0446\u0435\u043d\u0437\u0456\u044f\/Peer review : 14. 01.2020 \u0440. \u041d\u0430\u0434\u0440\u0443\u043a\u043e\u0432\u0430\u043d\u0430\/Printed : 14.02.2020 \u0440. \u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443 \u041e\u0442\u0440\u0438\u043c\u0430\u043d\u043e \u0433\u0440\u0430\u043d\u0443\u043b\u044f\u0442 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0456 \u0441\u0430\u043f\u043e\u043d\u0456\u0442\u043e\u0432\u043e\u0457 […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[13],"tags":[],"_links":{"self":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/1127"}],"collection":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1127"}],"version-history":[{"count":3,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/1127\/revisions"}],"predecessor-version":[{"id":5085,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/1127\/revisions\/5085"}],"wp:attachment":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1127"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1127"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1127"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}