{"id":1275,"date":"2021-01-15T22:42:27","date_gmt":"2021-01-15T20:42:27","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=1275"},"modified":"2021-03-03T14:15:44","modified_gmt":"2021-03-03T12:15:44","slug":"%d1%80%d0%be%d0%b7%d1%80%d0%be%d0%b1%d0%ba%d0%b0-%d1%82%d0%b0-%d0%b2%d0%b8%d0%ba%d0%be%d1%80%d0%b8%d1%81%d1%82%d0%b0%d0%bd%d0%bd%d1%8f-%d0%b3%d1%96%d0%b1%d1%80%d0%b8%d0%b4%d0%bd%d0%b8%d1%85-%d0%bf","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=1275","title":{"rendered":"\u0420\u043e\u0437\u0440\u043e\u0431\u043a\u0430 \u0442\u0430 \u0432\u0438\u043a\u043e\u0440\u0438\u0441\u0442\u0430\u043d\u043d\u044f \u0433\u0456\u0431\u0440\u0438\u0434\u043d\u0438\u0445 \u043f\u0456\u0433\u043c\u0435\u043d\u0442\u0456\u0432 \u0443 \u043f\u043e\u043a\u0440\u0438\u0432\u043d\u043e\u043c\u0443 \u043e\u0437\u0434\u043e\u0431\u043b\u0435\u043d\u043d\u0456 \u0448\u043a\u0456\u0440"},"content":{"rendered":"

\u0420\u041e\u0417\u0420\u041e\u0411\u041a\u0410 \u0422\u0410 \u0412\u0418\u041a\u041e\u0420\u0418\u0421\u0422\u0410\u041d\u041d\u042f \u0413\u0406\u0411\u0420\u0418\u0414\u041d\u0418\u0425 \u041f\u0406\u0413\u041c\u0415\u041d\u0422\u0406\u0412 \u0423 \u041f\u041e\u041a\u0420\u0418\u0412\u041d\u041e\u041c\u0423 \u041e\u0417\u0414\u041e\u0411\u041b\u0415\u041d\u041d\u0406 \u0428\u041a\u0406\u0420<\/p>\n

PREPARATION AND APPLICATION OF HYBRID PIGMENTS FOR FINISHING LEATHER<\/p>\n

 <\/p>\n

<\/a> \u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 26-35. \u041d\u043e\u043c\u0435\u0440: \u21162, 2020 (283)<\/strong><\/p>\n

\u0410\u0432\u0442\u043e\u0440\u0438:<\/strong>
\n\u0410.\u041e. \u0411\u041e\u041d\u0414\u0410\u0420\u0404\u0412\u0410, \u041e.\u0420. \u041c\u041e\u041a\u0420\u041e\u0423\u0421\u041e\u0412\u0410
\n\u041a\u0438\u0457\u0432\u0441\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0442\u043e\u0440\u0433\u043e\u0432\u0435\u043b\u044c\u043d\u043e-\u0435\u043a\u043e\u043d\u043e\u043c\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442
\n\u041e.\u0410. \u041e\u0425\u041c\u0410\u0422
\n\u041a\u0438\u0457\u0432\u0441\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442 \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0439 \u0442\u0430 \u0434\u0438\u0437\u0430\u0439\u043d\u0443
\n\u0410.\u041e. BONDARYEVA, \u041e.R. MOKROUSOVA
\nKyiv National University of Trade And Economics
\n\u041e.\u0410. OKHMAT
\nKyiv National University of Technologies And Design<\/p>\n

DOI:<\/strong> https:\/\/www.doi.org\/10.31891\/2307-5732-2020-283-2-26-35<\/a><\/p>\n

\u0420\u0435\u0446\u0435\u043d\u0437\u0456\u044f\/Peer review :<\/strong> 25.4.2020\u0440.
\n\u041d\u0430\u0434\u0440\u0443\u043a\u043e\u0432\u0430\u043d\u0430\/Printed :<\/strong> 16.6.2020 \u0440.<\/p>\n

\u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443<\/strong><\/p>\n

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\n\u041a\u043b\u044e\u0447\u043e\u0432\u0456 \u0441\u043b\u043e\u0432\u0430:<\/strong> \u043c\u043e\u043d\u0442\u043c\u043e\u0440\u0438\u043b\u043e\u043d\u0456\u0442, \u0430\u043d\u0456\u043e\u043d\u043d\u0438\u0439 \u0431\u0430\u0440\u0432\u043d\u0438\u043a, \u043c\u043e\u0434\u0438\u0444\u0456\u043a\u0430\u0446\u0456\u044f, \u0430\u0431\u0441\u043e\u0440\u0431\u0446\u0456\u044f, \u043f\u0456\u0433\u043c\u0435\u043d\u0442, \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f, \u043e\u0437\u0434\u043e\u0431\u043b\u0435\u043d\u043d\u044f \u0448\u043a\u0456\u0440.<\/p>\n

\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n

\u00a0 \u00a0 The aim of the research is the development of a hybrid pigment based on modified montmorillonite and anionic dyes for effective coating of genuine leather. The efficiency of adsorption of anionic dyes on cationic montmorillonite is investigated. Was identified a high level of adsorption of anionic dyes at pH 5-6.5. The role of the dye structure, the level of the critical concentration of micelle formation on the dye adsorption on the surface of montmorillonite is provided. It is proposed to use a stepwise modification of montmorillonite with hydroxochrome complexes, followed by adsorption of anionic dyes on its cationic surface to obtain hybrid pigments. The optimal composition of hybrid pigments, which are characterized by intensity and color stability in a wide range of pH, is proposed. Hybrid pigments are resistant to deposition and delamination over time, have a high coating ability and pH level for effective combination with film formers in the coating composition for leather finishing. The optimal composition of hybrid pigments of black, dark green and blue colors is proposed. The obtained pigments are used for the coating of leather, as a result of which high indicators of coating quality are achieved.
\nKey words:<\/strong> montmorillonite, anionic dye, modification, absorption, pigment, coating, leather finishing.<\/p>\n

References<\/strong><\/p>\n

    \n
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  23. Danylkovych A. H. Tekhnolohiia i materialy vyrobnytstva shkiry : navch. posib. \/ Danylkovych A. H., Mokrousova O. R., Okhmat O. A. \u2013 Kyiv : Feniks, 2009. \u2013 580 s.<\/li>\n
  24. Shkira dlia verkhu vzuttia. Tekhnichni umovy : DSTU 2726-94 (HOST 939-94). \u2013 [Chynnyi vid 01-01-1996]. \u2013 Kyiv : Derzhspozhyvstandart Ukrainy, 1996. 19 s.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

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