{"id":13428,"date":"2022-08-21T11:14:33","date_gmt":"2022-08-21T08:14:33","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=13428"},"modified":"2022-10-03T14:54:54","modified_gmt":"2022-10-03T11:54:54","slug":"synthesis-and-structural-characterization-of-zno-nanoparticles","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=13428","title":{"rendered":"Synthesis and structural characterization of ZNO nanoparticles"},"content":{"rendered":"

<\/p>\n

SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF ZnO NANOPARTICLES<\/p>\n

\u0421\u0418\u041d\u0422\u0415\u0417 \u0406 \u0421\u0422\u0420\u0423\u041a\u0422\u0423\u0420\u041d\u0410 \u0425\u0410\u0420\u0410\u041a\u0422\u0415\u0420\u0418\u0421\u0422\u0418\u041a\u0410 \u041d\u0410\u041d\u041e\u0427\u0410\u0421\u0422\u0418\u041d\u041e\u041a ZnO<\/p>\n

\u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438:\u00a0<\/strong>35<\/strong>–<\/strong>41<\/strong>. \u041d\u043e\u043c\u0435\u0440: \u21164, 2022 (311)\u00a0\u00a0 \"\"<\/a> <\/strong>
\n\u0410\u0432\u0442\u043e\u0440\u0438:<\/strong>
\nTatyana ASAULYUK
\nhttps:\/\/orcid.org\/0000-0001-5961-6895<\/a>
\ne-mail: tatisevna@gmail.com<\/a>
\nKherson National Technical University
\nYulia SARIBYEKOVA
\nhttps:\/\/orcid.org\/0000-0001-6430-6509<\/a>
\ne-mail: ysaribyekova@gmail.com<\/a>
\nKherson National Technical University
\nOlga SEMESHKO
\nhttps:\/\/orcid.org\/0000-0002-8309-5273<\/a>
\ne-mail: solgaya@gmail.com<\/a>
\nKherson National Technical University
\nIrina KULISH
\nhttps:\/\/orcid.org\/0000-0002-0961-5904<\/a>
\ne-mail: kulish.in.411@gmail.com<\/a>
\nKherson National Technical University
\n\u0410\u0421\u0410\u0423\u041b\u042e\u041a \u0422. \u0421., \u0421\u0410\u0420\u0406\u0411\u0404\u041a\u041e\u0412\u0410 \u042e.\u0413., \u0421\u0415\u041c\u0415\u0428\u041a\u041e \u041e.\u042f., \u041a\u0423\u041b\u0406\u0428 \u0406.\u041c.
\n\u0425\u0435\u0440\u0441\u043e\u043d\u0441\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0442\u0435\u0445\u043d\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442
\nDOI:<\/strong>\u00a0https:\/\/www.doi.org\/10.31891\/2307-5732-2022-311-4-35-41<\/a><\/p>\n

\u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443<\/strong><\/p>\n

In the present work, zinc oxide (ZnO) nanoparticles were synthesized by direct precipitation method in aqueous solution using zinc acetate dihydrate and sodium hydroxide as precursors. The molar ratio of Zn2+<\/sup> to OH–<\/sup> was 1:2. The obtained precipitated compound was treated at different temperatures. The crystal phase and structural parameters of each prepared ZnO samples such as interplanar spacing, crystallite size, dislocation density, micro strain were determined by X-ray diffraction (XRD) analysis for different crystallographic planes. Other crystallite parameters such as lattice constants, unit cell volume, Zn\u2013O bond length, crystallinity of synthesized ZnO samples also were calculated from the XRD data. The XRD patterns show the successfully synthetized ZnO phase with wurtzite hexagonal structure and average crystallite sizes of 24.6 nm, 25.6 nm and 28.1 nm for the samples that dried at room temperature without heat treatment (S1), dried at 60\u00b0C without calcination (S2), dried at 60\u00b0C and calcinated at 300\u00b0C in air atmosphere for 2 hours (S3) respectively. The calculated structural parameters of the synthesized ZnO nanoparticles are in good agreement with the standard reported data (JCPDS 36-1451). The effect of heat treatment on the structural parameters of synthesized ZnO nanoparticles was examined and it indicates that increasing the thermal decomposition temperature improves the quality of crystalline material. The XRD data show that the synthesized S3 sample was free of impurities and characterized by lattice constants a\u00a0=\u00a03.252\u00a0\u00c5, c\u00a0=\u00a05.210\u00a0\u00c5, unit cell volume V\u00a0=\u00a047.703\u00a0\u00c53<\/sup>, bond length Zn\u2013O\u00a0=\u00a01.9789\u00a0\u00c5 and crystallinity 93%. The results are of practical value for simple synthesis of highly dispersed forms of ZnO and its possible application in textile finishing.
\nKeywords:<\/strong>\u00a0 ZnO, nanoparticles, precipitation, structure, XRD.<\/p>\n

\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u00a0\u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n

\u0423 \u0434\u0430\u043d\u0456\u0439 \u0440\u043e\u0431\u043e\u0442\u0456 \u043d\u0430\u043d\u043e\u0447\u0430\u0441\u0442\u0438\u043d\u043a\u0438 \u0446\u0438\u043d\u043a\u0443 \u043e\u043a\u0441\u0438\u0434\u0443 (ZnO) \u0441\u0438\u043d\u0442\u0435\u0437\u043e\u0432\u0430\u043d\u0456 \u043c\u0435\u0442\u043e\u0434\u043e\u043c \u043f\u0440\u044f\u043c\u043e\u0433\u043e \u043e\u0441\u0430\u0434\u0436\u0435\u043d\u043d\u044f \u0443 \u0432\u043e\u0434\u043d\u043e\u043c\u0443 \u0440\u043e\u0437\u0447\u0438\u043d\u0456 \u0437 \u0432\u0438\u043a\u043e\u0440\u0438\u0441\u0442\u0430\u043d\u043d\u044f\u043c \u0446\u0438\u043d\u043a\u0443 \u0430\u0446\u0435\u0442\u0430\u0442\u0443 \u0434\u0438\u0433\u0456\u0434\u0440\u0430\u0442\u0443 \u0456 \u043d\u0430\u0442\u0440\u0456\u044e \u0433\u0456\u0434\u0440\u043e\u043a\u0441\u0438\u0434\u0443 \u044f\u043a \u043f\u0440\u0435\u043a\u0443\u0440\u0441\u043e\u0440\u0456\u0432. \u041c\u043e\u043b\u044f\u0440\u043d\u0435 \u0441\u043f\u0456\u0432\u0432\u0456\u0434\u043d\u043e\u0448\u0435\u043d\u043d\u044f Zn2+<\/sup> \u0434\u043e OH–<\/sup> \u0441\u043a\u043b\u0430\u0434\u0430\u043b\u043e 1:2. \u041e\u0442\u0440\u0438\u043c\u0430\u043d\u0438\u0439 \u043e\u0441\u0430\u0434 \u043e\u0431\u0440\u043e\u0431\u043b\u044f\u043b\u0438 \u043f\u0440\u0438 \u0440\u0456\u0437\u043d\u0438\u0445 \u0442\u0435\u043c\u043f\u0435\u0440\u0430\u0442\u0443\u0440\u0430\u0445. \u041a\u0440\u0438\u0441\u0442\u0430\u043b\u0456\u0447\u043d\u0443 \u0444\u0430\u0437\u0443 \u0456 \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u0456 \u043f\u0430\u0440\u0430\u043c\u0435\u0442\u0440\u0438 \u043a\u043e\u0436\u043d\u043e\u0433\u043e \u043e\u0442\u0440\u0438\u043c\u0430\u043d\u043e\u0433\u043e \u0437\u0440\u0430\u0437\u043a\u0430, \u0442\u0430\u043a\u0456 \u044f\u043a \u043c\u0456\u0436\u043f\u043b\u043e\u0449\u0438\u043d\u043d\u0430 \u0432\u0456\u0434\u0441\u0442\u0430\u043d\u044c, \u0440\u043e\u0437\u043c\u0456\u0440 \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u0456\u0442\u0456\u0432, \u0449\u0456\u043b\u044c\u043d\u0456\u0441\u0442\u044c \u0434\u0438\u0441\u043b\u043e\u043a\u0430\u0446\u0456\u0439, \u043c\u0456\u043a\u0440\u043e\u043d\u0430\u043f\u0440\u0443\u0436\u0435\u043d\u043d\u044f, \u0432\u0438\u0437\u043d\u0430\u0447\u0430\u043b\u0438 \u0437\u0430 \u0434\u043e\u043f\u043e\u043c\u043e\u0433\u043e\u044e \u0440\u0435\u043d\u0442\u0433\u0435\u043d\u043e\u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u043e\u0433\u043e \u0430\u043d\u0430\u043b\u0456\u0437\u0443 (XRD) \u0434\u043b\u044f \u0440\u0456\u0437\u043d\u0438\u0445 \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u043e\u0433\u0440\u0430\u0444\u0456\u0447\u043d\u0438\u0445 \u043f\u043b\u043e\u0449\u0438\u043d. \u0406\u043d\u0448\u0456 \u043f\u0430\u0440\u0430\u043c\u0435\u0442\u0440\u0438 \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u0456\u0442\u0443, \u0442\u0430\u043a\u0456 \u044f\u043a \u043a\u043e\u043d\u0441\u0442\u0430\u043d\u0442\u0438 \u0440\u0435\u0448\u0456\u0442\u043a\u0438, \u043e\u0431\u2019\u0454\u043c \u0435\u043b\u0435\u043c\u0435\u043d\u0442\u0430\u0440\u043d\u043e\u0457 \u043a\u043e\u043c\u0456\u0440\u043a\u0438, \u0434\u043e\u0432\u0436\u0438\u043d\u0430 \u0437\u0432\u2019\u044f\u0437\u043a\u0443 Zn\u2013O, \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u0456\u0447\u043d\u0456\u0441\u0442\u044c \u0441\u0438\u043d\u0442\u0435\u0437\u043e\u0432\u0430\u043d\u0438\u0445 \u0437\u0440\u0430\u0437\u043a\u0456\u0432 ZnO, \u0442\u0430\u043a\u043e\u0436 \u0440\u043e\u0437\u0440\u0430\u0445\u043e\u0432\u0443\u0432\u0430\u043b\u0438 \u0437\u0430 \u0434\u0430\u043d\u0438\u043c\u0438 XRD. \u0420\u0435\u043d\u0442\u0433\u0435\u043d\u043e\u0433\u0440\u0430\u043c\u0438 \u0434\u0435\u043c\u043e\u043d\u0441\u0442\u0440\u0443\u044e\u0442\u044c \u0443\u0441\u043f\u0456\u0448\u043d\u043e \u0441\u0438\u043d\u0442\u0435\u0437\u043e\u0432\u0430\u043d\u0443 \u0444\u0430\u0437\u0443 ZnO \u0437 \u0433\u0435\u043a\u0441\u0430\u0433\u043e\u043d\u0430\u043b\u044c\u043d\u043e\u044e \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043e\u044e \u0432\u044e\u0440\u0446\u0438\u0442\u0443 \u0456 \u0441\u0435\u0440\u0435\u0434\u043d\u0456\u043c\u0438 \u0440\u043e\u0437\u043c\u0456\u0440\u0430\u043c\u0438 \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u0456\u0442\u0456\u0432 24,6 \u043d\u043c, 25,6 \u043d\u043c \u0456 28,1 \u043d\u043c \u0434\u043b\u044f \u0437\u0440\u0430\u0437\u043a\u0456\u0432, \u0432\u0438\u0441\u0443\u0448\u0435\u043d\u0438\u0445 \u043f\u0440\u0438 \u043a\u0456\u043c\u043d\u0430\u0442\u043d\u0456\u0439 \u0442\u0435\u043c\u043f\u0435\u0440\u0430\u0442\u0443\u0440\u0456 \u0431\u0435\u0437 \u0442\u0435\u0440\u043c\u043e\u043e\u0431\u0440\u043e\u0431\u043a\u0438 (S1), \u0432\u0438\u0441\u0443\u0448\u0435\u043d\u0438\u0445 \u043f\u0440\u0438 60\u00b0C \u0431\u0435\u0437 \u043f\u0440\u043e\u0436\u0430\u0440\u044e\u0432\u0430\u043d\u043d\u044f (S2), \u0432\u0438\u0441\u0443\u0448\u0435\u043d\u0438\u0445 \u043f\u0440\u0438 60\u00b0C \u0456 \u043e\u0431\u0440\u043e\u0431\u043b\u0435\u043d\u0438\u0445 \u043f\u0440\u0438 300\u00b0C \u0432 \u0430\u0442\u043c\u043e\u0441\u0444\u0435\u0440\u0456 \u043f\u043e\u0432\u0456\u0442\u0440\u044f \u043f\u0440\u043e\u0442\u044f\u0433\u043e\u043c 2 \u0433\u043e\u0434 (S3), \u0432\u0456\u0434\u043f\u043e\u0432\u0456\u0434\u043d\u043e. \u0420\u043e\u0437\u0440\u0430\u0445\u043e\u0432\u0430\u043d\u0456 \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u0456 \u043f\u0430\u0440\u0430\u043c\u0435\u0442\u0440\u0438 \u0441\u0438\u043d\u0442\u0435\u0437\u043e\u0432\u0430\u043d\u0438\u0445 \u043d\u0430\u043d\u043e\u0447\u0430\u0441\u0442\u0438\u043d\u043e\u043a ZnO \u0434\u043e\u0431\u0440\u0435 \u0443\u0437\u0433\u043e\u0434\u0436\u0443\u044e\u0442\u044c\u0441\u044f \u0437\u0456 \u0441\u0442\u0430\u043d\u0434\u0430\u0440\u0442\u043d\u0438\u043c\u0438 \u0437\u0432\u0456\u0442\u043d\u0438\u043c\u0438 \u0434\u0430\u043d\u0438\u043c\u0438 (JCPDS 36-1451). \u0414\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u043e \u0432\u043f\u043b\u0438\u0432 \u0442\u0435\u0440\u043c\u0456\u0447\u043d\u043e\u0457 \u043e\u0431\u0440\u043e\u0431\u043a\u0438 \u043d\u0430 \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u0456 \u043f\u0430\u0440\u0430\u043c\u0435\u0442\u0440\u0438 \u0441\u0438\u043d\u0442\u0435\u0437\u043e\u0432\u0430\u043d\u0438\u0445 \u043d\u0430\u043d\u043e\u0447\u0430\u0441\u0442\u0438\u043d\u043e\u043a ZnO, \u044f\u043a\u0438\u0439 \u0441\u0432\u0456\u0434\u0447\u0438\u0442\u044c \u043f\u0440\u043e \u0442\u0435, \u0449\u043e \u043f\u0456\u0434\u0432\u0438\u0449\u0435\u043d\u043d\u044f \u0442\u0435\u043c\u043f\u0435\u0440\u0430\u0442\u0443\u0440\u0438 \u0442\u0435\u0440\u043c\u0456\u0447\u043d\u043e\u0433\u043e \u0440\u043e\u0437\u043a\u043b\u0430\u0434\u0443 \u043f\u043e\u043a\u0440\u0430\u0449\u0443\u0454 \u044f\u043a\u0456\u0441\u0442\u044c \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u0456\u0447\u043d\u043e\u0433\u043e \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0443. \u0414\u0430\u043d\u0456 XRD \u043f\u043e\u043a\u0430\u0437\u0443\u044e\u0442\u044c, \u0449\u043e \u0441\u0438\u043d\u0442\u0435\u0437\u043e\u0432\u0430\u043d\u0438\u0439 \u0437\u0440\u0430\u0437\u043e\u043a S3 \u043d\u0435 \u043c\u0456\u0441\u0442\u0438\u0442\u044c \u0434\u043e\u043c\u0456\u0448\u043e\u043a \u0456 \u0445\u0430\u0440\u0430\u043a\u0442\u0435\u0440\u0438\u0437\u0443\u0454\u0442\u044c\u0441\u044f \u043f\u0430\u0440\u0430\u043c\u0435\u0442\u0440\u0430\u043c\u0438 \u0440\u0435\u0448\u0456\u0442\u043a\u0438 a\u00a0=\u00a03.252\u00a0\u00c5, c\u00a0=\u00a05.210\u00a0\u00c5, \u043e\u0431\u2019\u0454\u043c\u043e\u043c \u0435\u043b\u0435\u043c\u0435\u043d\u0442\u0430\u0440\u043d\u043e\u0457 \u043a\u043e\u043c\u0456\u0440\u043a\u0438 V\u00a0=\u00a047.703\u00a0\u00c53<\/sup>, \u0434\u043e\u0432\u0436\u0438\u043d\u043e\u044e \u0437\u0432\u2019\u044f\u0437\u043a\u0443 Zn\u2013O\u00a0=\u00a01.9789\u00a0\u00c5 \u0456 \u043a\u0440\u0438\u0441\u0442\u0430\u043b\u0456\u0447\u043d\u0456\u0441\u0442\u044e 93%. \u0420\u0435\u0437\u0443\u043b\u044c\u0442\u0430\u0442\u0438 \u043c\u0430\u044e\u0442\u044c \u043f\u0440\u0430\u043a\u0442\u0438\u0447\u043d\u0435 \u0437\u043d\u0430\u0447\u0435\u043d\u043d\u044f \u0434\u043b\u044f \u043f\u0440\u043e\u0441\u0442\u043e\u0433\u043e \u0441\u0438\u043d\u0442\u0435\u0437\u0443 \u0432\u0438\u0441\u043e\u043a\u043e\u0434\u0438\u0441\u043f\u0435\u0440\u0441\u043d\u0438\u0445 \u0444\u043e\u0440\u043c ZnO \u0456 \u0457\u0445 \u043c\u043e\u0436\u043b\u0438\u0432\u043e\u0433\u043e \u0437\u0430\u0441\u0442\u043e\u0441\u0443\u0432\u0430\u043d\u043d\u044f \u0432 \u043e\u043f\u043e\u0440\u044f\u0434\u0436\u0435\u043d\u043d\u0456 \u0442\u0435\u043a\u0441\u0442\u0438\u043b\u044e.
\n\u041a\u043b\u044e\u0447\u043e\u0432\u0456 \u0441\u043b\u043e\u0432\u0430:<\/strong> ZnO, \u043d\u0430\u043d\u043e\u0447\u0430\u0441\u0442\u0438\u043d\u043a\u0438, \u043e\u0441\u0430\u0434\u0436\u0435\u043d\u043d\u044f, \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u0430, XRD.<\/p>\n

References<\/strong><\/p>\n

    \n
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