{"id":15871,"date":"2023-02-11T22:28:20","date_gmt":"2023-02-11T20:28:20","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=15871"},"modified":"2023-03-24T13:47:29","modified_gmt":"2023-03-24T11:47:29","slug":"elektroosadzhennya-ta-vlastyvosti-zaliznyh-pokryttiv-oderzhanyh-u-magnitnomu-poli-nyzkoyi-indukcziyi","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=15871","title":{"rendered":"\u0415\u043b\u0435\u043a\u0442\u0440\u043e\u043e\u0441\u0430\u0434\u0436\u0435\u043d\u043d\u044f \u0442\u0430 \u0432\u043b\u0430\u0441\u0442\u0438\u0432\u043e\u0441\u0442\u0456 \u0437\u0430\u043b\u0456\u0437\u043d\u0438\u0445 \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u0456\u0432 \u043e\u0434\u0435\u0440\u0436\u0430\u043d\u0438\u0445 \u0443 \u043c\u0430\u0433\u043d\u0456\u0442\u043d\u043e\u043c\u0443 \u043f\u043e\u043b\u0456 \u043d\u0438\u0437\u044c\u043a\u043e\u0457 \u0456\u043d\u0434\u0443\u043a\u0446\u0456\u0457"},"content":{"rendered":"

<\/p>\n

\u0415\u041b\u0415\u041a\u0422\u0420\u041e\u041e\u0421\u0410\u0414\u0416\u0415\u041d\u041d\u042f \u0422\u0410 \u0412\u041b\u0410\u0421\u0422\u0418\u0412\u041e\u0421\u0422\u0406 \u0417\u0410\u041b\u0406\u0417\u041d\u0418\u0425 \u041f\u041e\u041a\u0420\u0418\u0422\u0422\u0406\u0412 \u041e\u0414\u0415\u0420\u0416\u0410\u041d\u0418\u0425 \u0423 \u041c\u0410\u0413\u041d\u0406\u0422\u041d\u041e\u041c\u0423 \u041f\u041e\u041b\u0406 \u041d\u0418\u0417\u042c\u041a\u041e\u0407 \u0406\u041d\u0414\u0423\u041a\u0426\u0406\u0407<\/p>\n

ELECTRODEPOSITION AND PROPERTIES OF IRON DEPOSITS OBTAINED IN A MAGNETIC FIELD OF WEAK INDUCTION<\/p>\n

\u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 74-79. \u041d\u043e\u043c\u0435\u0440: \u2116<\/strong>6<\/strong>.\u0442.2, 2022 (315) <\/strong>\"\"<\/a>
\nDOI:<\/strong> https:\/\/www.doi.org\/10.31891\/2307-5732-2022-315-6(2)-74-79<\/a>
\n\u0410<\/strong>\u0432\u0442\u043e\u0440\u0438<\/strong>: <\/strong>
\n\u0412\u043b\u0430\u0434\u0438\u0441\u043b\u0430\u0432\u0430 \u041c\u0406\u0429\u0415\u041d\u041a\u041e
\n\u0423\u043a\u0440\u0430\u0457\u043d\u0441\u044c\u043a\u0438\u0439 \u0434\u0435\u0440\u0436\u0430\u0432\u043d\u0438\u0439 \u0445\u0456\u043c\u0456\u043a\u043e-\u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442
\nhttps:\/\/orcid.org\/0000-0002-1867-3874<\/a>
\ne-mail: vlada@ua.fm
\n\u0421\u0442\u0430\u043d\u0456\u0441\u043b\u0430\u0432 \u041a\u041e\u0412\u0410\u041b\u042c\u041e\u0412
\n\u0423\u043a\u0440\u0430\u0457\u043d\u0441\u044c\u043a\u0438\u0439 \u0434\u0435\u0440\u0436\u0430\u0432\u043d\u0438\u0439 \u0445\u0456\u043c\u0456\u043a\u043e-\u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442
\nhttps:\/\/orcid.org\/0000-0001-8839-2392<\/a>
\ne-mail: sv_kovalyov@i.ua
\nVladyslava MISHCHENKO, Stanislav KOVALYOV
\nUkrainian State University of Chemical Technology<\/p>\n

\u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443<\/strong><\/p>\n

\u00a0<\/strong>\u0412 \u0440\u043e\u0431\u043e\u0442\u0456 \u043d\u0430\u0432\u0435\u0434\u0435\u043d\u043e \u0440\u0435\u0437\u0443\u043b\u044c\u0442\u0430\u0442\u0438 \u0434\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u044c \u0435\u043b\u0435\u043a\u0442\u0440\u043e\u043e\u0441\u0430\u0434\u0436\u0435\u043d\u043d\u044f \u0442\u0430 \u0432\u043b\u0430\u0441\u0442\u0438\u0432\u043e\u0441\u0442\u0456 \u0437\u0430\u043b\u0456\u0437\u043d\u0438\u0445 \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u0456\u0432 \u043e\u0434\u0435\u0440\u0436\u0430\u043d\u0438\u0445 \u0435\u043b\u0435\u043a\u0442\u0440\u043e\u043a\u0440\u0438\u0441\u0442\u0430\u043b\u0456\u0437\u0430\u0446\u0456\u0454\u044e \u0443 \u043c\u0430\u0433\u043d\u0456\u0442\u043d\u043e\u043c\u0443 \u043f\u043e\u043b\u0456 \u043d\u0438\u0437\u044c\u043a\u043e\u0457 \u0456\u043d\u0434\u0443\u043a\u0446\u0456\u0457.
\n\u041a\u043b\u044e\u0447\u043e\u0432\u0456 \u0441\u043b\u043e\u0432\u0430:<\/strong> \u0435\u043b\u0435\u043a\u0442\u0440\u043e\u043e\u0441\u0430\u0434\u0436\u0435\u043d\u043d\u044f, \u043c\u0430\u0433\u043d\u0456\u0442\u043d\u0435 \u043f\u043e\u043b\u0435, \u0437\u0430\u043b\u0456\u0437\u043d\u0456 \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f, \u043a\u043e\u0440\u043e\u0437\u0456\u0439\u043d\u0430 \u0441\u0442\u0456\u0439\u043a\u0456\u0441\u0442\u044c, \u043c\u0456\u043a\u0440\u043e\u0442\u0432\u0435\u0440\u0434\u0456\u0441\u0442\u044c.<\/p>\n

\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u00a0\u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n

The paper presented the electrodeposition, morphology and properties of iron deposits were obtained using a low-induction magnetic field of 0.001 T in the electrocrystallization process. The vector of magnetic field induction was directed perpendicular to the electrode surface. Iron deposits were obtained in an electrolyte FeSO4<\/sub>\u00b77H2<\/sub>O \u2013 1.5 mol\/l and Al2<\/sub>(SO4<\/sub>)3<\/sub>\u00b718H2<\/sub>O \u2013 0.15 mol\/l. The current density was 7 A\/dm2<\/sup>. Deposits were obtained on a copper base. The influence of the magnetic field on the process of electrodeposition of deposits was studied using the method of stationary potentiometry and cyclic voltammetry. Determination of the influence of the magnetic field on the morphology of deposits was carried out using scanning electron microscopy. Determination of the properties of the obtained iron deposits was carried out by measuring microhardness, reflectivity and corrosion resistance. Studies have shown that a magnetic field with an inductance of 0.001 T affects the processes of electrodeposition of an iron deposit, increasing its overvoltage by more than 1 volt. The morphology of the deposits does not change significantly, but the crystallites obtained in the magnetic field have a more rounded shape and the surface of the deposit is more uniform. The microhardness of deposits obtained by electrodeposition without the use of a magnetic field was 2610 MPa, and with a magnetic field – 2720 MPa. The reflectivity of deposits obtained in a magnetic field is 17% higher. The corrosion resistance of deposits obtained in a magnetic field is approximately two times higher. After conducting corrosion studies, the microhardness of the deposits obtained using a magnetic field did not change (2630 MPa), however, the microhardness of the deposits obtained under normal conditions decreased by approximately two times. Electrolysis parameters for maximum corrosion resistance, microhardness and reflectivity are proposed in the work.
\nKey words:<\/strong> electrodeposition, magnetic field, iron deposits, corrosion resistance, microhardness.<\/p>\n

\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n

    \n
  1. Coey J. M. D., Hings G. Magnetic electrodeposition \/\/ Journal of Alloys and Compounds. \u2013 2001. \u2013 \u2116 326. \u2013 P. 238 \u2013 245.<\/li>\n
  2. Chopart J.-P., Aaboubi O., Merienne E. MHD-control on limiting Faradaic currents \/\/ Energy Conversion and Management. \u2013 2002. \u2013 \u2116 43. \u2013 P. 365 \u2013 371.<\/li>\n
  3. Bund A., Koehler S., Kuehnlein H. H. Magnetic field effects in electrochemical reactions \/\/ Electrochimica Acta. \u2013 2003. \u2013 \u2116 49. \u2013 P. 147 \u2013 152.<\/li>\n
  4. Coey J. M. D., Rhen F. M. F., Dunne P. The magnetic concentration gradient force \u2014 Is it real? \/\/ J Solid State Electrochem. \u2013 2007. \u2013 \u2116 11. \u2013 P. 711 \u2013 717. \u2013 DOI: 1007\/s10008-006-0254-4.<\/li>\n
  5. Mutschke G., Bund A. On the 3D character of the magnetohydrodynamic effect during metal electrodeposition in cuboid cells \/\/ Electrochemistry Communications. \u2013 2008. \u2013 \u2116 10. \u2013 P. 597 \u2013 601.<\/li>\n
  6. Matsushima H., Nohira T., Mogi I. Effects of magnetic field on iron electrodeposition \/\/ Surface and Coatings Technology. \u2013 2004. \u2013 \u2116 179. \u2013 P. 245 \u2013 251. – DOI:10.1016\/S0257-8972(03)00860-0.<\/li>\n
  7. K\u00f6mpe K., K\u00fchl E., Nagorny K. Magnetic and Structural Properties of Electrodeposited Iron on Copper and Silver \/\/ Hyperfine Interactions. \u2013 2002. \u2013 \u2116 141\/142. \u2013 P. 419 \u2013 424.<\/li>\n
  8. Koza J., Uhlemann M., Gebert A. The effect of magnetic fields on the electrodeposition of iron \/\/ J Solid State Electrochem. \u2013 2008. \u2013 \u2116 12. \u2013 P. 181 \u2013 192. – DOI:1007\/s10008-007-0379-0.<\/li>\n
  9. Gu Z. H., Fahidy T. Z. On the effect of a horizontal magnetic field on the electrolytic deposition of thin Fe-Ni films \/\/ J. Phys. D: Appl. Phys. \u2013 2000. \u2013 \u2116 33. \u2013 P. 113 \u2013 114.<\/li>\n
  10. \u041a\u043e\u0432\u0430\u043b\u044c\u043e\u0432 \u0421.\u0412, \u041d\u0430\u0443\u043c\u0435\u043d\u043a\u043e \u041e.\u041f., \u041c\u0456\u0449\u0435\u043d\u043a\u043e \u0412.\u0406. \u041f\u043e\u0440\u0456\u0432\u043d\u044f\u043d\u043d\u044f \u0442\u0430 \u043f\u043e\u043b\u0456\u043f\u0448\u0435\u043d\u043d\u044f \u0442\u0435\u043f\u043b\u043e\u043e\u0431\u043c\u0456\u043d\u043d\u0438\u0445 \u0430\u043f\u0430\u0440\u0430\u0442\u0456\u0432 \u0445\u0430\u0440\u0447\u043e\u0432\u0438\u0445 \u0432\u0438\u0440\u043e\u0431\u043d\u0438\u0446\u0442\u0432 \u0448\u043b\u044f\u0445\u043e\u043c \u0437\u043c\u0456\u0446\u043d\u0435\u043d\u043d\u044f \u0434\u0435\u0442\u0430\u043b\u0435\u0439 \u0435\u043b\u0435\u043a\u0442\u0440\u043e\u0445\u0456\u043c\u0456\u0447\u043d\u0438\u043c \u043e\u0441\u0430\u0434\u043e\u043c \u0443 \u0441\u043b\u0430\u0431\u043a\u043e\u043c\u0443 \u043c\u0430\u0433\u043d\u0456\u0442\u043d\u043e\u043c\u0443 \u043f\u043e\u043b\u0456 \/\/ \u041f\u0440\u0430\u0446\u0456 \u0422\u0430\u0432\u0440\u0456\u0439\u0441\u044c\u043a\u043e\u0433\u043e \u0434\u0435\u0440\u0436\u0430\u0432\u043d\u043e\u0433\u043e \u0430\u0433\u0440\u043e\u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0447\u043d\u043e\u0433\u043e \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442\u0443: \u043d\u0430\u0443\u043a\u043e\u0432\u0435 \u0444\u0430\u0445\u043e\u0432\u0435 \u0432\u0438\u0434\u0430\u043d\u043d\u044f \/ \u0422\u0414\u0410\u0422\u0423. \u041c\u0435\u043b\u0456\u0442\u043e\u043f\u043e\u043b\u044c: \u0422\u0414\u0410\u0422\u0423. \u2013 \u2013, \u0422. 1, \u0432\u0438\u043f. 21. \u2013 \u00a0\u0421. 28-34.<\/li>\n
  11. Kovalyov S. V., Girin \u041e. B., Debiemme-Chouvy C., Mishchenko V. I. Copper electrodeposition under a weak magnetic field: Effect on the texturing and properties of the deposits \/\/ Journal of Applied Electrochemistry. \u2013 2021. \u2013 Vol. 51, \u2116 11. \u2013 \u0420. 1 \u2013 9. – DOI:1007\/s10800-020-01492-3.<\/li>\n<\/ol>\n

    References<\/strong><\/p>\n

      \n
    1. Coey J. M. D., Hings G. Magnetic electrodeposition \/\/ Journal of Alloys and Compounds. \u2013 2001. \u2013 \u2116 326. \u2013 P. 238 \u2013 245.<\/li>\n
    2. Chopart J.-P., Aaboubi O., Merienne E. MHD-control on limiting Faradaic currents \/\/ Energy Conversion and Management. \u2013 2002. \u2013 \u2116 43. \u2013 P. 365 \u2013 371.<\/li>\n
    3. Bund A., Koehler S., Kuehnlein H. H. Magnetic field effects in electrochemical reactions \/\/ Electrochimica Acta. \u2013 2003. \u2013 \u2116 49. \u2013 P. 147 \u2013 152.<\/li>\n
    4. Coey J. M. D., Rhen F. M. F., Dunne P. The magnetic concentration gradient force \u2014 Is it real? \/\/ J Solid State Electrochem. \u2013 2007. \u2013 \u2116 11. \u2013 P. 711 \u2013 717. \u2013 DOI:10.1007\/s10008-006-0254-4.<\/li>\n
    5. Mutschke G., Bund A. On the 3D character of the magnetohydrodynamic effect during metal electrodeposition in cuboid cells \/\/ Electrochemistry Communications. \u2013 2008. \u2013 \u2116 10. \u2013 P. 597 \u2013 601.<\/li>\n
    6. Matsushima H., Nohira T., Mogi I. Effects of magnetic field on iron electrodeposition \/\/ Surface and Coatings Technology. \u2013 2004. \u2013 \u2116 179. \u2013 P. 245 \u2013 251. – DOI:10.1016\/S0257-8972(03)00860-0.<\/li>\n
    7. K\u00f6mpe K., K\u00fchl E., Nagorny K. Magnetic and Structural Properties of Electrodeposited Iron on Copper and Silver \/\/ Hyperfine Interactions. \u2013 2002. \u2013 \u2116 141\/142. \u2013 P. 419 \u2013 424.<\/li>\n
    8. Koza J., Uhlemann M., Gebert A. The effect of magnetic fields on the electrodeposition of iron \/\/ J Solid State Electrochem. \u2013 2008. \u2013 \u2116 12. \u2013 P. 181 \u2013 192. – DOI:10.1007\/s10008-007-0379-0.<\/li>\n
    9. Gu Z. H., Fahidy T. Z. On the effect of a horizontal magnetic field on the electrolytic deposition of thin Fe-Ni films \/\/ J. Phys. D: Appl. Phys. \u2013 2000. \u2013 \u2116 33. \u2013 P. 113 \u2013 114.<\/li>\n
    10. Kovalyov S.V, Naumenko O.P., Mishchenko V.I. Porivniannia ta polipshennia teploobminnykh aparativ kharchovykh vyrobnytstv shliakhom zmitsnennia detalei elektrokhimichnym osadom u slabkomu mahnitnomu poli \/\/ Pratsi Tavriiskoho derzhavnoho ahrotekhnolohichnoho universytetu: naukove fakhove vydannia \/ TDATU. Melitopol: TDATU. \u2013 \u2013, T. 1, vyp. 21. \u2013\u00a0 S. 28-34.<\/li>\n
    11. Kovalyov S. V., Girin \u041e. B., Debiemme-Chouvy C., Mishchenko V. I. Copper electrodeposition under a weak magnetic field: Effect on the texturing and properties of the deposits \/\/ Journal of Applied Electrochemistry. \u2013 2021. \u2013 Vol. 51, \u2116 11. \u2013 \u0420. 1 \u2013 9. \u2013 DOI:10.1007\/s10800-020-01492-3.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":3,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[75],"tags":[],"_links":{"self":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/15871"}],"collection":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=15871"}],"version-history":[{"count":4,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/15871\/revisions"}],"predecessor-version":[{"id":16430,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/15871\/revisions\/16430"}],"wp:attachment":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=15871"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=15871"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=15871"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}