{"id":15885,"date":"2023-02-11T22:33:19","date_gmt":"2023-02-11T20:33:19","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=15885"},"modified":"2023-03-24T13:40:21","modified_gmt":"2023-03-24T11:40:21","slug":"zastosuvannya-gibrydnyh-pigmentiv-u-formuvanni-polimerno-mineralnogo-pokryttya-dlya-ozdoblennya-shkir","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=15885","title":{"rendered":"\u0417\u0430\u0441\u0442\u043e\u0441\u0443\u0432\u0430\u043d\u043d\u044f \u0433\u0456\u0431\u0440\u0438\u0434\u043d\u0438\u0445 \u043f\u0456\u0433\u043c\u0435\u043d\u0442\u0456\u0432 \u0443 \u0444\u043e\u0440\u043c\u0443\u0432\u0430\u043d\u043d\u0456 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u043e-\u043c\u0456\u043d\u0435\u0440\u0430\u043b\u044c\u043d\u043e\u0433\u043e \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f \u0434\u043b\u044f \u043e\u0437\u0434\u043e\u0431\u043b\u0435\u043d\u043d\u044f \u0448\u043a\u0456\u0440"},"content":{"rendered":"<p><!--more--><\/p>\n<p style=\"text-align: center;\">\u0417\u0410\u0421\u0422\u041e\u0421\u0423\u0412\u0410\u041d\u041d\u042f \u0413\u0406\u0411\u0420\u0418\u0414\u041d\u0418\u0425 \u041f\u0406\u0413\u041c\u0415\u041d\u0422\u0406\u0412 \u0423 \u0424\u041e\u0420\u041c\u0423\u0412\u0410\u041d\u041d\u0406 \u041f\u041e\u041b\u0406\u041c\u0415\u0420\u041d\u041e-\u041c\u0406\u041d\u0415\u0420\u0410\u041b\u042c\u041d\u041e\u0413\u041e \u041f\u041e\u041a\u0420\u0418\u0422\u0422\u042f \u0414\u041b\u042f \u041e\u0417\u0414\u041e\u0411\u041b\u0415\u041d\u041d\u042f \u0428\u041a\u0406\u0420<\/p>\n<p style=\"text-align: center;\">THE APPLICATION OF HYBRID PIGMENTS IN THE FORMATION OF A POLYMER-MINERAL COATING FOR LEATHER FINISHING<\/p>\n<p><strong>\u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 25-31. \u041d\u043e\u043c\u0435\u0440: \u2116<\/strong><strong>6<\/strong><strong>.\u0442.2, 2022 (315)\u00a0\u00a0<\/strong> <a href=\"http:\/\/journals.khnu.km.ua\/vestnik\/wp-content\/uploads\/2023\/02\/vknu-ts-2022-n6t2315-25-31.pdf\"> <img loading=\"lazy\" class=\"size-full wp-image-69 alignnone\" src=\"http:\/\/journals.khnu.km.ua\/vestnik\/wp-content\/uploads\/2021\/01\/pdf.png\" alt=\"\" width=\"76\" height=\"32\" \/><\/a><br \/>\n<strong>DOI:<\/strong> <a href=\"https:\/\/www.doi.org\/10.31891\/2307-5732-2022-315-6(2)-25-31\">https:\/\/www.doi.org\/10.31891\/2307-5732-2022-315-6(2)-25-31<\/a><br \/>\n<strong>\u0410<\/strong><strong>\u0432\u0442\u043e\u0440\u0438<\/strong><strong>: <\/strong><br \/>\n\u0410\u043d\u043d\u0430 \u0411\u041e\u041d\u0414\u0410\u0420\u0404\u0412\u0410<br \/>\n\u0414\u0435\u0440\u0436\u0430\u0432\u043d\u0438\u0439 \u0442\u043e\u0440\u0433\u043e\u0432\u0435\u043b\u044c\u043d\u043e-\u0435\u043a\u043e\u043d\u043e\u043c\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442<br \/>\n<a href=\"https:\/\/orcid.org\/0000-0002-3241-2726\">https:\/\/orcid.org\/0000-0002-3241-2726<\/a><br \/>\ne-mail: <a href=\"mailto:Aa-aa@i.ua\">Aa-aa@i.ua<\/a><br \/>\n\u041e\u043b\u0435\u043d\u0430 \u041c\u041e\u041a\u0420\u041e\u0423\u0421\u041e\u0412\u0410<br \/>\n\u0414\u0435\u0440\u0436\u0430\u0432\u043d\u0438\u0439 \u0442\u043e\u0440\u0433\u043e\u0432\u0435\u043b\u044c\u043d\u043e-\u0435\u043a\u043e\u043d\u043e\u043c\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442<br \/>\n<a href=\"https:\/\/orcid.org\/0000-0003-1943-8048\">https:\/\/orcid.org\/0000-0003-1943-8048<\/a><br \/>\ne-mail: olenamokrousova@gmail.com<br \/>\n\u0410nna BONDARYEVA, \u041elena MOKROUSOVA<br \/>\nState University Of Trade And Economics<br \/>\n<strong>\u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443<\/strong><br \/>\n\u0421\u0442\u0430\u0442\u0442\u044f \u043f\u0440\u0438\u0441\u0432\u044f\u0447\u0435\u043d\u0430 \u0434\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u043d\u044e \u0444\u0456\u0437\u0438\u043a\u043e-\u043c\u0435\u0445\u0430\u043d\u0456\u0447\u043d\u0438\u0445 \u0432\u043b\u0430\u0441\u0442\u0438\u0432\u043e\u0441\u0442\u0435\u0439 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0438\u0445 \u043f\u043b\u0456\u0432\u043e\u043a \u0432 \u0440\u0435\u0437\u0443\u043b\u044c\u0442\u0430\u0442\u0456 \u0437\u0430\u0441\u0442\u043e\u0441\u0443\u0432\u0430\u043d\u043d\u044f \u0433\u0456\u0431\u0440\u0438\u0434\u043d\u0438\u0445 \u043f\u0456\u0433\u043c\u0435\u043d\u0442\u0456\u0432 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0456 \u043c\u043e\u043d\u0442\u043c\u043e\u0440\u0438\u043b\u043e\u043d\u0456\u0442\u0443 \u0434\u043b\u044f \u0444\u043e\u0440\u043c\u0443\u0432\u0430\u043d\u043d\u044f \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u043e-\u043c\u0456\u043d\u0435\u0440\u0430\u043b\u044c\u043d\u043e\u0433\u043e \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f \u0434\u043b\u044f \u043e\u0437\u0434\u043e\u0431\u043b\u0435\u043d\u043d\u044f \u0448\u043a\u0456\u0440. \u0417\u0430\u043f\u0440\u043e\u043f\u043e\u043d\u043e\u0432\u0430\u043d\u043e\u0433\u043e \u043c\u0435\u0445\u0430\u043d\u0456\u0437\u043c\u0443 \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u0443\u0432\u0430\u043d\u043d\u044f \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u043e\u0457 \u043c\u0430\u0442\u0440\u0438\u0446\u0456 \u0433\u0456\u0431\u0440\u0438\u0434\u043d\u0438\u043c \u043f\u0456\u0433\u043c\u0435\u043d\u0442\u043e\u043c, \u0437\u0433\u0456\u0434\u043d\u043e \u044f\u043a\u043e\u0433\u043e \u0432\u0438\u0441\u043e\u043a\u043e\u0440\u043e\u0437\u0432\u0438\u043d\u0435\u043d\u0430 \u0441\u043e\u0440\u0431\u0446\u0456\u0439\u043d\u0430 \u043f\u043e\u0432\u0435\u0440\u0445\u043d\u044f \u043c\u043e\u043d\u0442\u043c\u043e\u0440\u0438\u043b\u043e\u043d\u0456\u0442\u0443 \u0441\u043f\u0440\u0438\u044f\u0454 \u0430\u0434\u0441\u043e\u0440\u0431\u0446\u0456\u0457 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u0443 \u0442\u0430 \u0441\u0442\u0430\u0431\u0456\u043b\u0456\u0437\u0443\u0454 \u0439\u043e\u0433\u043e \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u0443. \u0417\u0430\u0441\u0442\u043e\u0441\u0443\u0432\u0430\u043d\u043d\u044f \u0433\u0456\u0431\u0440\u0438\u0434\u043d\u0438\u0445 \u043f\u0456\u0433\u043c\u0435\u043d\u0442\u0456\u0432 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0456 \u043c\u043e\u043d\u0442\u043c\u043e\u0440\u0438\u043b\u043e\u043d\u0456\u0442\u0443 \u0437\u0430\u0431\u0435\u0437\u043f\u0435\u0447\u0443\u0454 \u043f\u0456\u0434\u0432\u0438\u0449\u0435\u043d\u043d\u044f \u0444\u0456\u0437\u0438\u043a\u043e-\u043c\u0435\u0445\u0430\u043d\u0456\u0447\u043d\u0438\u0445 \u0432\u043b\u0430\u0441\u0442\u0438\u0432\u043e\u0441\u0442\u0435\u0439 \u043f\u043e\u043a\u0440\u0438\u0432\u043d\u0438\u0445 \u043f\u043b\u0456\u0432\u043e\u043a, \u043f\u043b\u0430\u0441\u0442\u0438\u0444\u0456\u043a\u0443\u0454 \u0442\u0430 \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u0443\u0454 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0443 \u043a\u043e\u043c\u043f\u043e\u0437\u0438\u0446\u0456\u044e, \u0441\u043f\u0440\u0438\u044f\u0454 \u043e\u0442\u0440\u0438\u043c\u0430\u043d\u043d\u044e \u0448\u043a\u0456\u0440 \u0437 \u0432\u0438\u0441\u043e\u043a\u0438\u043c\u0438 \u0435\u043a\u0441\u043f\u043b\u0443\u0430\u0442\u0430\u0446\u0456\u0439\u043d\u0438\u043c\u0438 \u0445\u0430\u0440\u0430\u043a\u0442\u0435\u0440\u0438\u0441\u0442\u0438\u043a\u0430\u043c\u0438 \u0437\u0430 \u043f\u043e\u043a\u0430\u0437\u043d\u0438\u043a\u0430\u043c\u0438 \u0430\u0434\u0433\u0435\u0437\u0456\u0457 \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f \u0434\u043e \u043c\u043e\u043a\u0440\u043e\u0457 \u0442\u0430 \u0441\u0443\u0445\u043e\u0457 \u0448\u043a\u0456\u0440\u0438, \u0441\u0442\u0456\u0439\u043a\u043e\u0441\u0442\u0456 \u0434\u043e \u043c\u043e\u043a\u0440\u043e\u0433\u043e \u0442\u0435\u0440\u0442\u044f \u0442\u0430 \u0434\u043e \u0431\u0430\u0433\u0430\u0442\u043e\u0440\u0430\u0437\u043e\u0432\u0438\u0445 \u0432\u0438\u0433\u0438\u043d\u0456\u0432.<br \/>\n<strong>\u041a\u043b\u044e\u0447\u043e\u0432\u0456 \u0441\u043b\u043e\u0432\u0430:<\/strong> \u0433\u0456\u0431\u0440\u0438\u0434\u043d\u0456 \u043f\u0456\u0433\u043c\u0435\u043d\u0442\u0438, \u043c\u043e\u043d\u0442\u043c\u043e\u0440\u0438\u043b\u043e\u043d\u0456\u0442, \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f, \u043e\u0437\u0434\u043e\u0431\u043b\u0435\u043d\u043d\u044f, \u0448\u043a\u0456\u0440\u0430, \u0432\u043b\u0430\u0441\u0442\u0438\u0432\u043e\u0441\u0442\u0456<\/p>\n<p style=\"text-align: center;\"><strong>\u00a0<\/strong><strong>\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u00a0\u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n<p>The paper is focused to the study of the physical and mechanical properties of a polymer-mineral coating based on hybrid pigments for leather finishing. The aim of this research is to study the effect of hybrid pigments based on montmorillonite on the formation of a polymer-mineral coating for leather finishing.<br \/>\nHybrid pigments obtained by complex modification of native montmorillonite with sodium carbonate and basic chromium (III) sulfate with further subsequent adsorption of anionic dyes on the cationic surface of the mineral particles were used for this research. A ready-made mixture of various structures film-formers, intended for the finishing of facial and polished leather was used as a film-former. For the leather finishing, coating paints were prepared in the form of polymer-mineral compositions by mixing hybrid pigments with a film-forming agent in the ratio, wt. part 1: 5.<br \/>\nIn this study it was calculated that montmorillonite consumption at the level of 1.5-2.0% in terms of the mass of montmorillonite from the mass of dry polymer residue was optimal for obtaining high physical and mechanical properties of polymer films for finishing leather. A mechanism for structuring the polymer matrix with a hybrid pigment was proposed. According to this mechanism the highly developed sorption surface of montmorillonite provided adsorption of the polymer and stabilized its structure with the formation of a mixed polymer-mineral composite. It was shown that the use of montmorillonite in the composition of hybrid pigment allowed to adjust the physical and mechanical properties of the polymer-mineral composition for leather finishing, provided an increase in strength and regulated the level of elasticity of the covering film, which ensured an increase in the operational properties of the leather coating.<br \/>\n<strong>Keywords:<\/strong> hybrid pigments, montmorillonite, coating, finishing, leather, properties<\/p>\n<p style=\"text-align: center;\"><strong>\u041b\u0456\u0442\u0435\u0440\u0430\u0442\u0443\u0440\u0430<\/strong><\/p>\n<p><strong>\u00a0<\/strong><span style=\"color: #737373; font-size: 1rem;\">Osgood m. J. Pigments in modern leather finishing. <\/span><em style=\"color: #737373; font-size: 1rem;\"> Soc. Leather. Technol. Chem<\/em><span style=\"color: #737373; font-size: 1rem;\">. 1990. Vol. 74, \u2116 1. P. 1-6.<\/span><\/p>\n<ol>\n<li>\u0411\u043e\u043d\u0434\u0430\u0440\u0454\u0432\u0430 \u0410. O., \u041c\u043e\u043a\u0440\u043e\u0443\u0441\u043e\u0432\u0430 \u041e. \u0420., \u041e\u0445\u043c\u0430\u0442 \u041e. \u0410. \u0420\u043e\u0437\u0440\u043e\u0431\u043a\u0430 \u0442\u0430 \u0432\u0438\u043a\u043e\u0440\u0438\u0441\u0442\u0430\u043d\u043d\u044f \u0433\u0456\u0431\u0440\u0438\u0434\u043d\u0438\u0445 \u043f\u0456\u0433\u043c\u0435\u043d\u0442\u0456\u0432 \u0443 \u043f\u043e\u043a\u0440\u0438\u0432\u043d\u043e\u043c\u0443 \u043e\u0437\u0434\u043e\u0431\u043b\u0435\u043d\u043d\u0456 \u0448\u043a\u0456\u0440. <em>\u0412\u0456\u0441\u043d\u0438\u043a \u0425\u041d\u0423. \u0422\u0435\u0445\u043d\u0456\u0447\u043d\u0456 \u043d\u0430\u0443\u043a\u0438<\/em>. 2020. \u2116 2 (283). \u0421. 26\u201335.<\/li>\n<li>\u041a\u0430\u0441\u044c\u044f\u043d \u0415. \u0404. \u0424\u0456\u0437\u0438\u043a\u043e-\u0445\u0456\u043c\u0456\u044f \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0438\u0445 \u043f\u043b\u0456\u0432\u043a\u043e\u0443\u0442\u0432\u043e\u0440\u044e\u0432\u0430\u0447\u0456\u0432 \u0434\u043b\u044f \u043e\u0437\u0434\u043e\u0431\u043b\u0435\u043d\u043d\u044f \u0448\u043a\u0456\u0440\u0438: \u043d\u0430\u0432\u0447. \u043f\u043e\u0441\u0456\u0431. \u041a\u0438\u0457\u0432 : \u041e\u0441\u0432\u0456\u0442\u0430 \u0423\u043a\u0440\u0430\u0457\u043d\u0438, 2019. 178 \u0441.<\/li>\n<li>\u0411\u043e\u043d\u0434\u0430\u0440\u0454\u0432\u0430 \u0410. \u041e., \u041c\u043e\u043a\u0440\u043e\u0443\u0441\u043e\u0432\u0430 \u041e. \u0420. \u0424\u043e\u0440\u043c\u0443\u0432\u0430\u043d\u043d\u044f \u0444\u0456\u0437\u0438\u043a\u043e-\u043c\u0435\u0445\u0430\u043d\u0456\u0447\u043d\u0438\u0445 \u0432\u043b\u0430\u0441\u0442\u0438\u0432\u043e\u0441\u0442\u0435\u0439 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u043e-\u043c\u0456\u043d\u0435\u0440\u0430\u043b\u044c\u043d\u043e\u0433\u043e \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f \u0434\u043b\u044f \u043e\u0437\u0434\u043e\u0431\u043b\u0435\u043d\u043d\u044f \u0448\u043a\u0456\u0440. <em>\u041c\u0456\u0436\u043d\u0430\u0440\u043e\u0434\u043d\u0438\u0439 \u043d\u0430\u0443\u043a\u043e\u0432\u043e-\u043f\u0440\u0430\u043a\u0442\u0438\u0447\u043d\u0438\u0439 \u0436\u0443\u0440\u043d\u0430\u043b \u00ab\u0422\u043e\u0432\u0430\u0440\u0438 \u0456 \u0440\u0438\u043d\u043a\u0438\u00bb. <\/em> \u2116 2. \u0421. 97\u2013109.<\/li>\n<li>\u041e\u0442\u0440\u043e\u0448\u043a\u043e \u0412. \u0410., \u041c\u043e\u043a\u0440\u043e\u0443\u0441\u043e\u0432\u0430 \u041e. \u0420., \u041c\u0435\u0440\u0435\u0436\u043a\u043e \u041d. \u0412. \u0412\u0437\u0430\u0454\u043c\u043e\u0434\u0456\u044f \u043a\u043e\u043b\u0430\u0433\u0435\u043d\u0443 \u0434\u0435\u0440\u043c\u0438 \u0437 \u043c\u0456\u043d\u0435\u0440\u0430\u043b\u044c\u043d\u0438\u043c\u0438 \u0442\u0430 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0438\u043c\u0438 \u0441\u043f\u043e\u043b\u0443\u043a\u0430\u043c\u0438. <em>\u0422\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0447\u043d\u0438\u0439 \u0430\u0443\u0434\u0438\u0442 \u0442\u0430 \u0440\u0435\u0437\u0435\u0440\u0432\u0438 \u0432\u0438\u0440\u043e\u0431\u043d\u0438\u0446\u0442\u0432\u0430<\/em>. 2016. \u2116 2\/4(28). \u0421. 48-54.<\/li>\n<li>Onur Y\u0131lmaz, Catalina N. Cheaburu, G\u00fcrb\u00fcz G\u00fcl\u00fcmser, Cornelia Vasile. Rheological behaviour of acrylate\/montmorillonite nanocomposite latexes and their application in leather finishing as binders. <em>Progress in Organic Coatings<\/em>. 2011. 70, Issue 1. P. 52\u201358.<\/li>\n<li>Zhang Xiaolei, Liu Liu Qinglan, Zhang Weiping. Nanocomposites of Acrylate-Organosilicon Resin\/Layered Silicate for Leather Finishing. <em> Soc. Leather. Technol. Chem<\/em>. 2006. \u2116 6. P. 188\u2013193.<\/li>\n<li>Ma Jianzhong, Zhang Zhijie, Liu Lingyun et al. Application of Acrylic Coating Agent Modified by Nano SiO<sub>2<\/sub>. <em> Soc. Leather. Technol. Chem<\/em>. 2006. \u2116 5. P. 250\u2013254.<\/li>\n<li>Onur Y\u0131lmaz, Aurica P. Chiriac, Catalina Natalia Cheaburu, Loredana E. Nita, G\u00fcrb\u00fcz G\u00fcl\u00fcmser, Donatella Duraccio, Sossio Cimmino, Cornelia Vasile. Nanocomposites based on montmorillonite\/acrylic copolymer for aqueous coating of soft surfaces. <em>Solid State Phenomena.<\/em>Vol.151. P. 129\u2013134.<\/li>\n<li>Onur Y\u0131lmaz. A hybrid polyacrylate\/OMMT nanocomposite latex: Synthesis, characterization and its application as a coating binder. <em>Progress in Organic Coatings<\/em>. 2014. 77, Issue 1. P. 110\u2013117.<\/li>\n<li>Yilmaz O., CheaburuN., Durraccio D., Gulumser G., Vasile C. Preparation of stable acrylate\/montmorillonite nanocomposite latex via <em>in situ<\/em> batch emulsion polymerization: Effect of clay types. <em>Applied Clay Science<\/em>. 2010. Vol. 49, Issue 3. P. 288\u2013297.<\/li>\n<li>\u041f\u0430\u0442\u0435\u043d\u0442 \u043d\u0430 \u043a\u043e\u0440\u0438\u0441\u043d\u0443 \u043c\u043e\u0434\u0435\u043b\u044c UA \u2116 144635 \u0423\u043a\u0440\u0430\u0457\u043d\u0430 \u041c\u041f\u041a \u042114\u0421 3\/06. \u0421\u043f\u043e\u0441\u0456\u0431 \u043e\u0442\u0440\u0438\u043c\u0430\u043d\u043d\u044f \u043f\u0456\u0433\u043c\u0435\u043d\u0442\u043d\u043e\u0433\u043e \u043a\u043e\u043d\u0446\u0435\u043d\u0442\u0440\u0430\u0442\u0443 \u0434\u043b\u044f \u043e\u0437\u0434\u043e\u0431\u043b\u0435\u043d\u043d\u044f \u0448\u043a\u0456\u0440 \/ \u0412\u0438\u043d\u0430\u0445\u0456\u0434\u043d\u0438\u043a\u0438 \u0411\u043e\u043d\u0434\u0430\u0440\u0454\u0432\u0430 \u0410. \u041e., \u041c\u043e\u043a\u0440\u043e\u0443\u0441\u043e\u0432\u0430 \u041e. \u0420., \u041e\u0445\u043c\u0430\u0442 \u041e. \u0410.; \u0437\u0430\u044f\u0432\u043d\u0438\u043a \u0456 \u043f\u0430\u0442\u0435\u043d\u0442\u043e\u0432\u043b\u0430\u0441\u043d\u0438\u043a: \u041a\u041d\u0422\u0415\u0423. \u2116 202003432; \u0437\u0430\u044f\u0432\u043b. 05.06.2020. \u043e\u043f\u0443\u0431\u043b. 12.10.2020. \u00ab\u041f\u0440\u043e\u043c\u0438\u0441\u043b\u043e\u0432\u0430 \u0432\u043b\u0430\u0441\u043d\u0456\u0441\u0442\u044c\u00bb, \u0431\u044e\u043b. \u2116 19\/2020.<\/li>\n<li>\u0414\u0430\u043d\u0438\u043b\u043a\u043e\u0432\u0438\u0447 \u0410. \u0413. \u041f\u0440\u0430\u043a\u0442\u0438\u043a\u0443\u043c \u0437 \u0445\u0456\u043c\u0456\u0457 \u0442\u0430 \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0457 \u0448\u043a\u0456\u0440\u0438 \u0442\u0430 \u0445\u0443\u0442\u0440\u0430: \u043d\u0430\u0432\u0447. \u043f\u043e\u0441\u0456\u0431\u043d\u0438\u043a, \u041a. : \u0424\u0435\u043d\u0456\u043a\u0441, 2006. 338 \u0441.<\/li>\n<li>\u041c\u0456\u043a\u0443\u043b\u044c\u043e\u043d\u043e\u043a \u0406. \u041e. \u0422\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0447\u043d\u0456 \u043e\u0441\u043d\u043e\u0432\u0438 \u043f\u0435\u0440\u0435\u0440\u043e\u0431\u043b\u0435\u043d\u043d\u044f \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0438\u0445 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0456\u0432 : \u043d\u0430\u0432\u0447. \u043f\u043e\u0441i\u0431. \u041a\u0438\u0457\u0432 : \u041a\u041f\u0406 \u0456\u043c. \u0406\u0433\u043e\u0440\u044f \u0421\u0456\u043a\u043e\u0440\u0441\u044c\u043a\u043e\u0433\u043e, \u0412\u0438\u0434-\u0432\u043e \u00ab\u041f\u043e\u043b\u0456\u0442\u0435\u0445\u043d\u0456\u043a\u0430\u00bb\u00bb, 2017. 324 \u0441.<\/li>\n<li>\u0414\u0421\u0422\u0423 2726-94. \u0428\u043a\u0456\u0440\u0430 \u0434\u043b\u044f \u0432\u0435\u0440\u0445\u0443 \u0432\u0437\u0443\u0442\u0442\u044f. \u0422\u0435\u0445\u043d\u0456\u0447\u043d\u0456 \u0443\u043c\u043e\u0432\u0438. [\u0427\u0438\u043d\u043d\u0438\u0439 \u0432\u0456\u0434 1996-01-01]. \u0412\u0438\u0434. \u043e\u0444\u0456\u0446. \u041a\u0438\u0457\u0432: \u0414\u0435\u0440\u0436\u0441\u043f\u043e\u0436\u0438\u0432\u0441\u0442\u0430\u043d\u0434\u0430\u0440\u0442 \u0423\u043a\u0440\u0430\u0457\u043d\u0438, 1995. 14 \u0441.<\/li>\n<\/ol>\n<p style=\"text-align: center;\"><strong>References<\/strong><\/p>\n<ol>\n<li>Osgood m. J. Pigments in modern leather finishing. <em> Soc. Leather. Technol. Chem<\/em>. 1990. Vol. 74, \u2116 1. P. 1-6.<\/li>\n<li>Bondarieva A. O., Mokrousova O. R., Okhmat O. A. Rozrobka ta vykorystannia hibrydnykh pihmentiv u pokryvnomu ozdoblenni shkir. <em>Herald of Khmelnytskyi National University. Technical sciences<\/em>. 2020. \u2116 2 (283). S. 26\u201335.<\/li>\n<li>Kasian E. Ye. Fizyko-khimiia polimernykh plivkoutvoriuvachiv dlia ozdoblennia shkiry: navch. posib. Kyiv : Osvita Ukrainy, 2019. 178 s.<\/li>\n<li>Bondarieva A. O., Mokrousova O. R. Formuvannia fizyko-mekhanichnykh vlastyvostei polimerno-mineralnoho pokryttia dlia ozdoblennia shkir. Mizhnarodnyi naukovo-praktychnyi zhurnal \u00abTovary i rynky\u00bb. 2020. \u2116 2. S. 97\u2013109.<\/li>\n<li>Otroshko V. A., Mokrousova O. R., Merezhko N. V. Vzaiemodiia kolahenu dermy z mineralnymy ta polimernymy spolukamy. <em>Tekhnolohichnyi audyt ta rezervy vyrobnytstva<\/em>. 2016. \u2116 2\/4(28). S. 48-54.<\/li>\n<li>Onur Y\u0131lmaz, Catalina N. Cheaburu, G\u00fcrb\u00fcz G\u00fcl\u00fcmser, Cornelia Vasile. Rheological behaviour of acrylate\/montmorillonite nanocomposite latexes and their application in leather finishing as binders. <em>Progress in Organic Coatings<\/em>. 2011. 70, Issue 1. P. 52\u201358.<\/li>\n<li>Zhang Xiaolei, Liu Liu Qinglan, Zhang Weiping. Nanocomposites of Acrylate-Organosilicon Resin\/Layered Silicate for Leather Finishing. <em> Soc. Leather. Technol. Chem<\/em>. 2006. \u2116 6. P. 188\u2013193.<\/li>\n<li>Ma Jianzhong, Zhang Zhijie, Liu Lingyun et al. Application of Acrylic Coating Agent Modified by Nano SiO<sub>2<\/sub>. <em> Soc. Leather. Technol. Chem<\/em>. 2006. \u2116 5. P. 250\u2013254.<\/li>\n<li>Onur Y\u0131lmaz, Aurica P. Chiriac, Catalina Natalia Cheaburu, Loredana E. Nita, G\u00fcrb\u00fcz G\u00fcl\u00fcmser, Donatella Duraccio, Sossio Cimmino, Cornelia Vasile. Nanocomposites based on montmorillonite\/acrylic copolymer for aqueous coating of soft surfaces. <em>Solid State Phenomena<\/em><em>.<\/em>Vol.151. P. 129\u2013134.<\/li>\n<li>Onur Y\u0131lmaz. A hybrid polyacrylate\/OMMT nanocomposite latex: Synthesis, characterization and its application as a coating binder. <em>Progress in Organic Coatings<\/em>. 2014. 77, Issue 1. P. 110\u2013117.<\/li>\n<li>Yilmaz O., CheaburuN., Durraccio D., Gulumser G., Vasile C. Preparation of stable acrylate\/montmorillonite nanocomposite latex via <em>in situ<\/em> batch emulsion polymerization: Effect of clay types. <em>Applied Clay Science<\/em>. 2010. Vol. 49, Issue 3. P. 288\u2013297.<\/li>\n<li>Patent na korysnu model UA \u2116 144635 Ukraina MPK S14S 3\/06. Sposib otrymannia pihmentnoho kontsentratu dlia ozdoblennia shkir \/ Vynakhidnyky Bondarieva A. O., Mokrousova O. R., Okhmat O. A.; zaiavnyk i patentovlasnyk: KNTEU. \u2116 202003432; zaiavl. 05.06.2020. opubl. 12.10.2020. \u00abPromyslova vlasnist\u00bb, biul. \u2116 19\/2020.<\/li>\n<li>Danylkovych A. H. Praktykum z khimii ta tekhnolohii shkiry ta khutra: navch. posibnyk, K. : Feniks, 2006. 338 s.<\/li>\n<li>Mikulonok I. O. Tekhnolohichni osnovy pereroblennia polimernykh materialiv : navch. posib. Kyiv : KPI im. Ihoria Sikorskoho, Vyd-vo \u00abPolitekhnika\u00bb\u00bb, 2017. 324 s.<\/li>\n<li>DSTU 2726-94. Shkira dlia verkhu vzuttia. Tekhnichni umovy. [Chynnyi vid 1996-01-01]. Vyd. ofits. Kyiv: Derzhspozhyvstandart Ukrainy, 1995. 14 s.<\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":3,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[75],"tags":[],"_links":{"self":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/15885"}],"collection":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=15885"}],"version-history":[{"count":5,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/15885\/revisions"}],"predecessor-version":[{"id":16414,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/15885\/revisions\/16414"}],"wp:attachment":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=15885"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=15885"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=15885"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}