{"id":1737,"date":"2021-01-16T19:19:20","date_gmt":"2021-01-16T17:19:20","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=1737"},"modified":"2021-04-19T11:34:02","modified_gmt":"2021-04-19T08:34:02","slug":"%d1%81%d0%b5%d0%bd%d1%81%d0%be%d1%80-%d0%bd%d0%b0-%d0%be%d1%81%d0%bd%d0%be%d0%b2%d1%96-%d0%b3%d0%b5%d1%82%d0%b5%d1%80%d0%be%d0%bc%d0%b5%d1%82%d0%b0%d0%bb%d1%96%d1%87%d0%bd%d0%be%d1%97-%d0%ba%d0%be","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=1737","title":{"rendered":"\u0421\u0435\u043d\u0441\u043e\u0440 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0456 \u0433\u0435\u0442\u0435\u0440\u043e\u043c\u0435\u0442\u0430\u043b\u0456\u0447\u043d\u043e\u0457 \u043a\u043e\u043c\u043f\u043b\u0435\u043a\u0441\u043d\u043e\u0457 \u0441\u043f\u043e\u043b\u0443\u043a\u0438 \u043a\u0443\u043f\u0440\u0443\u043c\u0443(\u0456\u0456) \u0437 n,n’-\u0431\u0456\u0441(\u0441\u0430\u043b\u0456\u0446\u0438\u043b\u0456\u0434\u0435\u043d)\u0442\u0456\u043e\u0441\u0435\u043c\u0438\u043a\u0430\u0440\u0431\u0430\u0437\u0438\u0434\u043e\u043c"},"content":{"rendered":"

\u0421\u0415\u041d\u0421\u041e\u0420 \u041d\u0410 \u041e\u0421\u041d\u041e\u0412\u0406 \u0413\u0415\u0422\u0415\u0420\u041e\u041c\u0415\u0422\u0410\u041b\u0406\u0427\u041d\u041e\u0407 \u041a\u041e\u041c\u041f\u041b\u0415\u041a\u0421\u041d\u041e\u0407 \u0421\u041f\u041e\u041b\u0423\u041a\u0418 \u041a\u0423\u041f\u0420\u0423\u041c\u0423(\u0406\u0406) \u0417 N,N’-\u0411\u0406\u0421(\u0421\u0410\u041b\u0406\u0426\u0418\u041b\u0406\u0414\u0415\u041d)\u0422\u0406\u041e\u0421\u0415\u041c\u0418\u041a\u0410\u0420\u0411\u0410\u0417\u0418\u0414\u041e\u041c<\/p>\n

SENSOR BASED ON HETEROMETALLIC COMPLEX COMPOUND COPPER(II) WITH N,N’-BIS(SALICYLIDENE)THIOSEMICARBAZIDE<\/p>\n

<\/a> \u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 169-175. \u041d\u043e\u043c\u0435\u0440: \u21165, 2019 (277)<\/strong>
\n\u0410\u0432\u0442\u043e\u0440\u0438: <\/strong>
\n\u041e.\u0412. \u041e\u0421\u0410\u0414\u0427\u0423\u041a, \u0412.\u0412. \u041c\u0410\u0420\u0422\u0418\u041d\u042e\u041a, \u0422.\u0406. \u0421\u0418\u0414\u041e\u0420\u0423\u041a
\n\u0412\u0456\u043d\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0442\u0435\u0445\u043d\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442
\n\u041c.\u0412. \u0404\u0412\u0421\u0404\u0404\u0412\u0410
\n\u0412\u0456\u043d\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u043c\u0435\u0434\u0438\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442 \u0456\u043c. \u041c. \u0406. \u041f\u0438\u0440\u043e\u0433\u043e\u0432\u0430
\n\u041e. V. OSADCHUK, V.V. MARTYNYUK, T.I. SYDORUK
\nVinnytsia National Technical University
\nM.V. EVSEEVA
\nNational Pirogov Memorial Medical University, Vinnytsya
\nDOI:<\/strong> https:\/\/www.doi.org\/10.31891\/2307-5732-2019-277-5-169-175<\/a>
\n\u0420\u0435\u0446\u0435\u043d\u0437\u0456\u044f\/Peer review :<\/strong> 05.06.2019 \u0440.
\n\u041d\u0430\u0434\u0440\u0443\u043a\u043e\u0432\u0430\u043d\u0430\/Printed :<\/strong> 23.07.2019 \u0440.<\/p>\n

\u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443<\/strong><\/p>\n

C\u0438\u043d\u0442\u0435\u0437\u043e\u0432\u0430\u043d\u043e \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b \u0433\u0435\u0442\u0435\u0440\u043e\u043c\u0435\u0442\u0430\u043b\u0456\u0447\u043d\u0438\u0439 \u043a\u0430\u043b\u044c\u0446\u0456\u0439 \u0434\u0438[N,N’-\u0431\u0456\u0441(\u0441\u0430\u043b\u0456\u0446\u0438\u043b\u0456\u0434\u0435\u043d)\u0442\u0456\u043e\u0441\u0435\u043c\u0438\u043a\u0430\u0440\u0431\u0430\u0437\u0438\u0434\u0430\u0442\u043e\u043a\u0443\u043f\u0440\u0430\u0442(\u0406\u0406)] \u0434\u0438\u0433\u0456\u0434\u0440\u0430\u0442, \u0442\u0430\u043a\u043e\u0433\u043e \u0441\u043a\u043b\u0430\u0434\u0443: Ca[CuL’]2<\/sub>\u00a0\u00b7\u00a02\u041d2<\/sub>\u041e, \u0434\u0435 L’ = C15<\/sub>H10<\/sub>N3<\/sub>O2<\/sub>S, \u043f\u0440\u043e\u0432\u0435\u0434\u0435\u043d\u043e \u0435\u043a\u0441\u043f\u0435\u0440\u0438\u043c\u0435\u043d\u0442\u0430\u043b\u044c\u043d\u0456 \u0432\u0438\u043c\u0456\u0440\u044e\u0432\u0430\u043d\u043d\u044f \u0442\u0430 \u0442\u0435\u043e\u0440\u0435\u0442\u0438\u0447\u043d\u0456 \u0440\u043e\u0437\u0440\u0430\u0445\u0443\u043d\u043a\u0438 \u043e\u0441\u043d\u043e\u0432\u043d\u0438\u0445 \u0444\u0456\u0437\u0438\u0447\u043d\u0438\u0445 \u043f\u0430\u0440\u0430\u043c\u0435\u0442\u0440\u0456\u0432 \u0434\u0430\u043d\u043e\u0433\u043e \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0443. \u0414\u043e\u0432\u0435\u0434\u0435\u043d\u043e, \u0449\u043e \u0434\u0430\u043d\u0438\u0439 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b \u0454 \u043d\u0430\u043f\u0456\u0432\u043f\u0440\u043e\u0432\u0456\u0434\u043d\u0438\u043a\u043e\u043c, \u043f\u0440\u0438\u0447\u043e\u043c\u0443 \u0437 \u043d\u043e\u0441\u0456\u044f\u043c\u0438 \u0437\u0430\u0440\u044f\u0434\u0443 \u043e\u0431\u043e\u0445 \u0437\u043d\u0430\u043a\u0456\u0432. \u041e\u0442\u0440\u0438\u043c\u0430\u043d\u043e \u0437\u0430\u043b\u0435\u0436\u043d\u043e\u0441\u0442\u0456 \u043f\u0438\u0442\u043e\u043c\u043e\u0433\u043e \u043e\u043f\u043e\u0440\u0443, \u043f\u0438\u0442\u043e\u043c\u043e\u0457 \u043f\u0440\u043e\u0432\u0456\u0434\u043d\u043e\u0441\u0442\u0456, \u043e\u043f\u043e\u0440\u0443, \u043a\u043e\u043d\u0446\u0435\u043d\u0442\u0440\u0430\u0446\u0456\u0457 \u043d\u043e\u0441\u0456\u0457\u0432 \u0437\u0430\u0440\u044f\u0434\u0443 \u0442\u0430 \u0441\u0442\u0430\u043b\u043e\u0457 \u0425\u043e\u043b\u043b\u0430 \u0432\u0456\u0434 \u0442\u0435\u043c\u043f\u0435\u0440\u0430\u0442\u0443\u0440\u0438. \u0412 \u0434\u0456\u0430\u043f\u0430\u0437\u043e\u043d\u0456 \u0442\u0435\u043c\u043f\u0435\u0440\u0430\u0442\u0443\u0440 \u0432\u0456\u0434 273 \u041a\u00a0 \u0434\u043e 493 \u041a \u043a\u043e\u043d\u0446\u0435\u043d\u0442\u0440\u0430\u0446\u0456\u044f \u043d\u043e\u0441\u0456\u0457\u0432 \u0437\u0430\u0440\u044f\u0434\u0443 \u0437\u0440\u043e\u0441\u0442\u0430\u0454 \u0432\u0456\u0434 1,11\u03871020\u00a0<\/sup>\u043c-3<\/sup> \u0434\u043e 2,61\u03871033<\/sup> \u043c-3<\/sup>, \u0430 \u0441\u0442\u0430\u043b\u0430 \u0425\u043e\u043b\u043b\u0430 \u0437\u043c\u0456\u043d\u044e\u0454\u0442\u044c\u0441\u044f \u0432\u0456\u0434 0,065 \u043c3<\/sup>\u0387\u041a\u043b-1<\/sup> \u0434\u043e 2,8\u038710-15<\/sup> \u043c3<\/sup>\u0387\u041a\u043b-1<\/sup>. \u041e\u0442\u0440\u0438\u043c\u0430\u043d\u043e \u0437\u0430\u043b\u0435\u0436\u043d\u043e\u0441\u0442\u0456 \u043d\u0430\u043f\u0440\u0443\u0433\u0438 \u0425\u043e\u043b\u043b\u0430 \u0442\u0430 \u043d\u0430\u043f\u0440\u0443\u0436\u0435\u043d\u043e\u0441\u0442\u0456 \u0435\u043b\u0435\u043a\u0442\u0440\u0438\u0447\u043d\u043e\u0433\u043e \u043f\u043e\u043b\u044f, \u0432\u0441\u0435\u0440\u0435\u0434\u0438\u043d\u0456 \u043f\u043b\u0430\u0441\u0442\u0438\u043d\u0438 \u0440\u043e\u0437\u043c\u0456\u0440\u0430\u043c\u0438 0,5\u00d70,5\u00d70,15 \u043c\u043c, \u0432\u0456\u0434 \u0456\u043d\u0434\u0443\u043a\u0446\u0456\u0457 \u043c\u0430\u0433\u043d\u0456\u0442\u043d\u043e\u0433\u043e \u043f\u043e\u043b\u044f.
\n\u041a\u043b\u044e\u0447\u043e\u0432\u0456 \u0441\u043b\u043e\u0432\u0430:<\/strong> \u0456\u043d\u0434\u0443\u043a\u0446\u0456\u044f, \u043c\u0430\u0433\u043d\u0456\u0442\u043d\u0435 \u043f\u043e\u043b\u0435, \u043a\u043e\u043d\u0446\u0435\u043d\u0442\u0440\u0430\u0446\u0456\u044f, \u043d\u0430\u043f\u0456\u0432\u043f\u0440\u043e\u0432\u0456\u0434\u043d\u0438\u043a, \u0433\u0435\u0442\u0435\u0440\u043e\u043c\u0435\u0442\u0430\u043b\u0456\u0447\u043d\u0456 \u043a\u043e\u043c\u043f\u043b\u0435\u043a\u0441\u043d\u0456 \u0441\u043f\u043e\u043b\u0443\u043a\u0438.<\/p>\n

\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n

The creation of new materials with specific physical properties that are used for making the sensors of temperature or magnetic field exists for a long time. From this point of view, of special interest are materials created based on heterometallic complex compounds. The synthesized material heterometallic Calcium di[N,N’-bis(salicylidene)thiosemicarbazidatocuprate(II)] dihydride, such a composition: Ca[CuL’]2<\/sub> \u00b7 2\u041d2<\/sub>\u041e, where L’ = C15<\/sub>H10<\/sub>N3<\/sub>O2<\/sub>S, experimental measurements and theoretical calculations of the basic physical parameters of this material are carried out. For a dedicated and dehydrated Ca complex compound[Cu(C15<\/sub>H10<\/sub>N3<\/sub>O2<\/sub>S)]2<\/sub> calculated molaro weight, which is equal to 759,829 g\/mol and the number of valence electrons in one molecule \u2013 210. For conducting experimental studies used a cylindrical specimen with a mass of 0.08 g and the amount 17,67\u221910-9<\/sup> m3<\/sup>, which were made from dehydrated compound (S) by pressing. Based on these data, we calculated the density of matter: \u03c1 = 4,527\u2219103 kg\/m3<\/sup>. It is proved that the material is a semiconductor, and charge carriers of both signs. The dependences of resistivity, conductivity, resistance, concentration of charge carriers and the Hall constant on temperature. In the temperature range from 273 K to 493 K, the resistivity varied from 2,04\u22191016<\/sup> \u03a9\u00b7m to 872,13 \u03a9\u00b7m, the resistance of the sample at a temperature of 273 K it is equal to 1.36\u00b71020<\/sup> \u03a9, at 313 K \u20132.02\u00b71016<\/sup> \u03a9, and at 493 K \u2013 5,8\u00b7106<\/sup> \u03a9, the concentration of charge carriers grows to 1,11\u00b71020<\/sup> m-3<\/sup> to 2,61\u00b71033 <\/sup>\u043c-3<\/sup>, and the Hall was changed from 0,065 m3<\/sup>\u00b7Cl-1<\/sup>: 2,8\u00b710-15<\/sup> m3<\/sup>\u00b7Cl-1<\/sup>. The dependences of the Hall voltage and electric field strength inside a plate with dimensions 0,5\u00d70,5\u00d70.15 mm, from the magnetic field induction. In the range from 0 to 100 mT Hall the voltage increases from 3,22\u00b710-17<\/sup> V to 3,22\u00b710-16<\/sup> V, from 100 mT to 1000 mT \u2013 Hall the voltage increases from 3,22\u00b710-16<\/sup> to\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 3,22\u00b710-15 <\/sup>V.
\nKey words:<\/strong> induction, magnetic field, concentration, semiconductor, heterometallic complex compounds.<\/p>\n

References<\/strong><\/p>\n

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  9. Panchenko T. Copper(II) and nickel(II) with N,N-bis(salicylidene)thiosemicarbazide heterometal complex compounds \/ T.\u00a0Panchenko, M. Evseeva, A. Ranskiy \/\/ Chem. & Chem. Technology. \u2013 2014. \u2013 Vol 8, \u2116 3. \u2013 P. 243\u2013248.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

    \u0421\u0415\u041d\u0421\u041e\u0420 \u041d\u0410 \u041e\u0421\u041d\u041e\u0412\u0406 \u0413\u0415\u0422\u0415\u0420\u041e\u041c\u0415\u0422\u0410\u041b\u0406\u0427\u041d\u041e\u0407 \u041a\u041e\u041c\u041f\u041b\u0415\u041a\u0421\u041d\u041e\u0407 \u0421\u041f\u041e\u041b\u0423\u041a\u0418 \u041a\u0423\u041f\u0420\u0423\u041c\u0423(\u0406\u0406) \u0417 N,N’-\u0411\u0406\u0421(\u0421\u0410\u041b\u0406\u0426\u0418\u041b\u0406\u0414\u0415\u041d)\u0422\u0406\u041e\u0421\u0415\u041c\u0418\u041a\u0410\u0420\u0411\u0410\u0417\u0418\u0414\u041e\u041c SENSOR BASED ON HETEROMETALLIC COMPLEX COMPOUND COPPER(II) WITH N,N’-BIS(SALICYLIDENE)THIOSEMICARBAZIDE \u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 169-175. \u041d\u043e\u043c\u0435\u0440: \u21165, 2019 (277) \u0410\u0432\u0442\u043e\u0440\u0438: \u041e.\u0412. \u041e\u0421\u0410\u0414\u0427\u0423\u041a, \u0412.\u0412. \u041c\u0410\u0420\u0422\u0418\u041d\u042e\u041a, \u0422.\u0406. \u0421\u0418\u0414\u041e\u0420\u0423\u041a \u0412\u0456\u043d\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0442\u0435\u0445\u043d\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442 \u041c.\u0412. \u0404\u0412\u0421\u0404\u0404\u0412\u0410 \u0412\u0456\u043d\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u043c\u0435\u0434\u0438\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442 \u0456\u043c. \u041c. \u0406. \u041f\u0438\u0440\u043e\u0433\u043e\u0432\u0430 \u041e. V. OSADCHUK, V.V. MARTYNYUK, T.I. SYDORUK Vinnytsia National Technical […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[18],"tags":[],"_links":{"self":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/1737"}],"collection":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1737"}],"version-history":[{"count":3,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/1737\/revisions"}],"predecessor-version":[{"id":5889,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/1737\/revisions\/5889"}],"wp:attachment":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1737"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1737"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1737"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}