{"id":2022,"date":"2021-01-18T18:34:24","date_gmt":"2021-01-18T16:34:24","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=2022"},"modified":"2021-04-14T14:11:18","modified_gmt":"2021-04-14T11:11:18","slug":"%d0%b4%d0%be%d1%81%d0%bb%d1%96%d0%b4%d0%b6%d0%b5%d0%bd%d0%bd%d1%8f-%d0%bf%d1%80%d0%be%d1%86%d0%b5%d1%81%d1%96%d0%b2-%d0%be%d1%87%d0%b8%d1%89%d0%b5%d0%bd%d0%bd%d1%8f-%d0%bd%d0%b0%d1%84%d1%82%d0%be","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=2022","title":{"rendered":"\u0414\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u043d\u044f \u043f\u0440\u043e\u0446\u0435\u0441\u0456\u0432 \u043e\u0447\u0438\u0449\u0435\u043d\u043d\u044f \u043d\u0430\u0444\u0442\u043e\u043f\u0440\u043e\u0434\u0443\u043a\u0442\u0456\u0432 \u0437\u0430 \u0434\u043e\u043f\u043e\u043c\u043e\u0433\u043e\u044e \u0430\u043a\u0442\u0438\u0432\u043e\u0432\u0430\u043d\u0438\u0445 \u0441\u043c\u0435\u043a\u0442\u0438\u0442\u043e\u0432\u0438\u0445 \u0433\u043b\u0438\u043d"},"content":{"rendered":"<p style=\"text-align: center;\">\u0414\u041e\u0421\u041b\u0406\u0414\u0416\u0415\u041d\u041d\u042f \u041f\u0420\u041e\u0426\u0415\u0421\u0406\u0412 \u041e\u0427\u0418\u0429\u0415\u041d\u041d\u042f \u041d\u0410\u0424\u0422\u041e\u041f\u0420\u041e\u0414\u0423\u041a\u0422\u0406\u0412 \u0417\u0410 \u0414\u041e\u041f\u041e\u041c\u041e\u0413\u041e\u042e \u0410\u041a\u0422\u0418\u0412\u041e\u0412\u0410\u041d\u0418\u0425 \u0421\u041c\u0415\u041a\u0422\u0418\u0422\u041e\u0412\u0418\u0425 \u0413\u041b\u0418\u041d<\/p>\n<p style=\"text-align: center;\">STUDY OF PROCESSES OF CLEANING OF OIL PRODUCTS ACCORDING TO ASSISTED SMECTITE CLAYS<\/p>\n<p><a href=\"http:\/\/journals.khnu.km.ua\/vestnik\/wp-content\/uploads\/2021\/01\/14-10.pdf\"><img src=\"http:\/\/journals.khnu.km.ua\/vestnik\/wp-content\/uploads\/2021\/01\/pdf.png\" \/><\/a> <strong>\u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 82-90. \u041d\u043e\u043c\u0435\u0440: \u21161, 2019 (269)<\/strong><br \/>\n<strong>\u0410\u0432\u0442\u043e\u0440\u0438:<\/strong><br \/>\n\u0410.\u042f. \u0413\u0410\u041d\u0417\u042e\u041a, \u0414.\u041c. \u0412\u0418\u0428\u041d\u0415\u0412\u0421\u042c\u041a\u0410, \u041d.\u041b. \u041f\u041e\u0425\u0418\u041b\u041e<br \/>\n\u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442<br \/>\n\u041e.\u041f. \u0428\u0415\u041b\u0415\u0421\u0422\u042e\u041a, \u041e.\u041c. \u041c\u0406\u0429\u0423\u041a<br \/>\n\u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0443\u043a\u043e\u0432\u043e-\u0434\u043e\u0441\u043b\u0456\u0434\u043d\u0438\u0439 \u0435\u043a\u0441\u043f\u0435\u0440\u0442\u043d\u043e-\u043a\u0440\u0438\u043c\u0456\u043d\u0430\u043b\u0456\u0441\u0442\u0438\u0447\u043d\u0438\u0439 \u0446\u0435\u043d\u0442\u0440 \u041c\u0412\u0421 \u0423\u043a\u0440\u0430\u0457\u043d\u0438<br \/>\nA.Y. GANZYUK,\u00a0 D.M. VISHNEVSKAYA, N.L. POHIULO<br \/>\nKhmelnytskyi National University<br \/>\nO.P. SHELESTIYK, O.M. MISHCHUK<br \/>\nKhmelnyskyi Research-Science Forensic Centre of Ministry of Internal Affairs of Ukraine<br \/>\n<strong>DOI:<\/strong> <a href=\"https:\/\/www.doi.org\/10.31891\/2307-5732-2019-269-1-82-90\">https:\/\/www.doi.org\/10.31891\/2307-5732-2019-269-1-82-90<\/a><br \/>\n<strong>\u0420\u0435\u0446\u0435\u043d\u0437\u0456\u044f\/Peer review :<\/strong> 17.11.2018 \u0440.<br \/>\n<strong>\u041d\u0430\u0434\u0440\u0443\u043a\u043e\u0432\u0430\u043d\u0430\/Printed :<\/strong> 15.02.2019 \u0440.<\/p>\n<p style=\"text-align: center;\"><strong>\u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443<\/strong><\/p>\n<p>\u0417 \u043c\u0435\u0442\u043e\u044e \u0437\u043c\u0435\u043d\u0448\u0435\u043d\u043d\u044f \u043d\u0435\u0433\u0430\u0442\u0438\u0432\u043d\u043e\u0433\u043e \u0432\u043f\u043b\u0438\u0432\u0443 \u043d\u0430 \u043d\u0430\u0432\u043a\u043e\u043b\u0438\u0448\u043d\u0454 \u0441\u0435\u0440\u0435\u0434\u043e\u0432\u0438\u0449\u0435 \u0442\u0430 \u0437\u0431\u0435\u0440\u0435\u0436\u0435\u043d\u043d\u044f \u0432\u043e\u0434\u043d\u0438\u0445 \u0440\u0435\u0441\u0443\u0440\u0441\u0456\u0432 \u0440\u043e\u0437\u0440\u043e\u0431\u043b\u0435\u043d\u0430 \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u044f \u043e\u0434\u0435\u0440\u0436\u0430\u043d\u043d\u044f \u0456 \u0432\u0438\u043a\u043e\u0440\u0438\u0441\u0442\u0430\u043d\u043d\u044f \u043d\u043e\u0432\u0438\u0445 \u0435\u0444\u0435\u043a\u0442\u0438\u0432\u043d\u0438\u0445 \u0441\u043e\u0440\u0431\u0435\u043d\u0442\u0456\u0432 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0456 \u043f\u0440\u0438\u0440\u043e\u0434\u043d\u0438\u0445 \u0430\u043b\u044e\u043c\u043e\u0441\u0438\u043b\u0456\u043a\u0430\u0442\u0456\u0432. \u0412 \u0440\u043e\u0431\u043e\u0442\u0456 \u0434\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u043e \u043c\u043e\u0436\u043b\u0438\u0432\u0456\u0441\u0442\u044c \u0432\u0438\u043a\u043e\u0440\u0438\u0441\u0442\u0430\u043d\u043d\u044f \u043c\u043e\u0434\u0438\u0444\u0456\u043a\u043e\u0432\u0430\u043d\u0438\u0445 \u0441\u0430\u043f\u043e\u043d\u0456\u0442\u043e\u0432\u0438\u0445 \u0433\u043b\u0438\u043d \u0443 \u044f\u043a\u043e\u0441\u0442\u0456 \u0435\u0444\u0435\u043a\u0442\u0438\u0432\u043d\u0438\u0445 \u0441\u043e\u0440\u0431\u0446\u0456\u0439\u043d\u0438\u0445 \u043c\u0430\u0442\u0435\u0440\u0456\u0430\u043b\u0456\u0432 \u0432 \u043f\u0440\u043e\u0446\u0435\u0441\u0430\u0445 \u043e\u0447\u0438\u0449\u0435\u043d\u043d\u044f \u043d\u0430\u0444\u0442\u043e\u043f\u0440\u043e\u0434\u0443\u043a\u0442\u0456\u0432. \u041f\u0440\u043e\u0430\u043d\u0430\u043b\u0456\u0437\u043e\u0432\u0430\u043d\u043e \u0457\u0445 \u0434\u0435\u0442\u0430\u043b\u044c\u043d\u0438\u0439 \u0432\u0443\u0433\u043b\u0435\u0432\u043e\u0434\u043d\u0435\u0432\u0438\u0439 \u0441\u043a\u043b\u0430\u0434 \u0442\u0430 \u043e\u0446\u0456\u043d\u0435\u043d\u043e \u043e\u0441\u043d\u043e\u0432\u043d\u0456 \u043f\u043e\u043a\u0430\u0437\u043d\u0438\u043a\u0438 \u0431\u0435\u043d\u0437\u0438\u043d\u0456\u0432 \u0434\u043e \u0442\u0430 \u043f\u0456\u0441\u043b\u044f \u043e\u0447\u0438\u0449\u0435\u043d\u043d\u044f. \u041e\u0442\u0440\u0438\u043c\u0430\u043d\u0456 \u0430\u043a\u0442\u0438\u0432\u043e\u0432\u0430\u043d\u0456 \u0444\u043e\u0440\u043c\u0438 \u043d\u0430 \u043e\u0441\u043d\u043e\u0432\u0456 \u0441\u0430\u043f\u043e\u043d\u0456\u0442\u043e\u0432\u0438\u0445 \u0433\u043b\u0438\u043d \u043c\u043e\u0436\u043d\u0430 \u0432\u0438\u043a\u043e\u0440\u0438\u0441\u0442\u043e\u0432\u0443\u0432\u0430\u0442\u0438 \u0432 \u044f\u043a\u043e\u0441\u0442\u0456 \u043d\u0430\u043f\u043e\u0432\u043d\u044e\u0432\u0430\u0447\u0456\u0432 \u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0438\u0445 \u0441\u0435\u0440\u0435\u0434\u043e\u0432\u0438\u0449 \u0456 \u043f\u043b\u0430\u0441\u0442\u0438\u0444\u0456\u043a\u0430\u0442\u043e\u0440\u0456\u0432, \u0430 \u0442\u0430\u043a\u043e\u0436 \u0443 \u0432\u0438\u0440\u043e\u0431\u043d\u0438\u0446\u0442\u0432\u0456 \u043d\u0430\u0444\u0442\u043e\u0432\u0438\u0445 \u0441\u043e\u0440\u0431\u0435\u043d\u0442\u0456\u0432.<br \/>\n<strong>\u041a\u043b\u044e\u0447\u043e\u0432\u0456 \u0441\u043b\u043e\u0432\u0430<\/strong>: \u0430\u0434\u0441\u043e\u0440\u0431\u0446\u0456\u044f, \u043d\u0430\u0444\u0442\u043e\u043f\u0440\u043e\u0434\u0443\u043a\u0442\u0438, \u0445\u0440\u043e\u043c\u0430\u0442\u043e\u0433\u0440\u0430\u0444\u0456\u044f, \u043e\u043a\u0442\u0430\u043d\u043e\u0432\u0435 \u0447\u0438\u0441\u043b\u043e, \u0441\u0430\u043f\u043e\u043d\u0456\u0442, \u0442\u0438\u0441\u043a \u043d\u0430\u0441\u0438\u0447\u0435\u043d\u043e\u0457 \u043f\u0430\u0440\u0438.<\/p>\n<p style=\"text-align: center;\"><strong>\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n<p><em>\u00a0<\/em>The possibility of modified saponite clays using as efficient sorption materials in the purification processes of petroleum products. The detailed hydrocarbon analysis of treated gasoline were made. The main characteristics of gasolines treated by modified saponite sorbents was estimated by chromatography methods. The possibility of modified saponite clays using as efficient sorption materials in the purification processes of petroleum products. The detailed hydrocarbon analysis of treated gasoline were made. The main characteristics of gasolines treated by modified saponite sorbents was estimated by chromatography methods. The saponite application in the forensic research to detect trace amounts of combustible liquids as material evidence from the place of fire were confirmed. We used natural mineral sorbents of different degrees of dispersion, their activated and modified forms for cleaning of gasoline with octane number 92 resulting in increase in octane number of gasoline up to 95 and more which was determined by research and motor methods. Treatment of gasoline by sorbent was carried out for 5 min. using ultrasound system then sorbent was separated by centrifugation and settled as sediment. Sorption capacity of hydrophobic sorbents for petroleum products is from 14.4 to 16.6 g\/g, sorption capacity for dissolved and emulsified petroleum is from 292 to 315 mg\/g. Refined gasoline was investigated using gas chromatography with high degree of resolution. Changes in the structure of clay have been analysed with infrared spectroscopy. As a conclusion, the obtaining of mineral sorption materials on the basis of saponite clay enables to use them as fillers of polymer environment and fluidizing agents, as well as in production of oil sorbents.<br \/>\n<strong>Keywords<\/strong>: adsorption, petroleum products, chromatography, octane rating, saponite, vapour pressure.<\/p>\n<p style=\"text-align: center;\"><strong>\u00a0<\/strong><strong>References<\/strong><\/p>\n<ol>\n<li>Klasyfikatsiia vydiv palyva [Elektronnyi resurs]. \u2013 Rezhym dostupu : http:\/\/ukrmap.su\/uk-g8\/869.html (Data zvernennia 05.10.2013)<\/li>\n<li>Chukaieva I.O. Formuvannia ukrainskoho rynku nafty i naftoproduktiv \/ I.O. Chukaieva \/\/ Ekonomika Ukrainy. \u2013 2001. \u2013 \u2116 2. \u2013 S. 84\u201386.<\/li>\n<li>Ekspluatatsiini kharakterystyky dyzelnoho palnoho [Elektronnyi resurs]. \u2013 Rezhym dostupu : http:\/\/ben4in.blogspot.com\/p\/blog-page_6269.html.<\/li>\n<li>Smidovich E.V. Tehnologija pererabotki nefti \/ E.V. Smidovich. \u2013 M. :Himija, 1980. \u2013 2. \u2013 328 s.<\/li>\n<li>Dubinin M.M. Adsorbcija i poristost&#8217; \/ M.M. Dubinin. \u2013 M. : VAHZ, 1972. \u2013 127 s.<\/li>\n<li>Thomas W.J. Adsorption technology and design \/ W.J. Thomas, B. Crittenden. \u2013 Oxford : Butterworth Heinemann, 1998. \u2013 R. 8\u201330.<\/li>\n<li>Kefer R.G. Adsorbenty, ih poluchenie, svojstva i primenenija \/ R.G.Kefer, N.F. Danilov. V.Z. Pojlov. \u2013 L. : Nauka, 1978. \u2013 204 s.<\/li>\n<li>Sokol H. M. Strukturna modyfikatsiia saponitovykh hlyn kyslotnoiu obrobkoiu \/ H. M. Sokol \/\/ Naukovi notatky : mizhvuzivskyi zbirnyk naukovykh prats \/ Lutskyi natsionalnyi tekhnichnyi universytet. \u2013 Lutsk, 2017. \u2013 \u2116 56. \u2013 S. 149\u2013153.<\/li>\n<li>Sokol H. M. Ochyshchennia naftoproduktiv ta vyluchennia yikh slidovykh kilkostei z pozhezhnoho smittia za dopomohoiu sorbtsiinykh materialiv dlia podalshoho doslidzhennia khromatohrafichnym metodom \/ H. M. Sokol, A. Ya. Hanziuk, O. P. Shelestiuk, O. M. Mishchuk \/\/ Herald of Khmelnytskyi National University. \u2013 Khmelnytskyi, 2017. \u2013 \u2116 1. \u2013 S. 87\u201394.<\/li>\n<li>Sokol G. M. Saponite is an environmentally friendly universal sorbent \/ G. M. Sokol, A. Y. Ganzyuk, D. S. Kamenskyh \/\/ Abstracts: Ninth International Scientific Congress \u201cA secure world understanding-trust-responsibility\u201d [CD supplament]. \u2013 Poznan, Poland, 4\u20137 July, 2013.<\/li>\n<li>Sokol G. M. Research of the adsorptivity of sorbents on the basis of natural mineral saponite \/ G. M. Sokol, S. A. Karvan, A. Y. Ganzyuk \/\/ Abstracts: International Conference \u201cModern Problems of Surface Chemistry\u201d Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kyiv, 20\u201321 May, 2014. \u2013 P. 179.<\/li>\n<li>Metody opredelenija frakcionnogo sostava : GOST 2177-99. \u2013 [Vzamen GOST 2177-82]. \u2013 Minsk : Mezhgos. sovet po standartizacii, metrologii i sertifikacii; K. : Goststandart Ukrainy, 1999. \u2013 23 s.<\/li>\n<li>Toplivo dlja dvigatelej. Issledovatel&#8217;skij metod opredelenija oktanovogo chisla : GOST 511-82. \u2013 Vzamen GOST 511-66. \u2013 SSSR: Postanovlenie Gosudarstvennogo komiteta SSSR po standartizacii ot 20.09.82. \u2013 14 s.<\/li>\n<li>Metod opredelenija benzola i summarnogo soderzhanija aromaticheskih uglevodorodov : GOST 29040-91 \/ SSSR : Postanovlenie Gosudarstvennogo komiteta SSSR po upravleniju kachestvom produkcii i standartom ot 26.06.91. \u2013 12 s.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"<p>\u0414\u041e\u0421\u041b\u0406\u0414\u0416\u0415\u041d\u041d\u042f \u041f\u0420\u041e\u0426\u0415\u0421\u0406\u0412 \u041e\u0427\u0418\u0429\u0415\u041d\u041d\u042f \u041d\u0410\u0424\u0422\u041e\u041f\u0420\u041e\u0414\u0423\u041a\u0422\u0406\u0412 \u0417\u0410 \u0414\u041e\u041f\u041e\u041c\u041e\u0413\u041e\u042e \u0410\u041a\u0422\u0418\u0412\u041e\u0412\u0410\u041d\u0418\u0425 \u0421\u041c\u0415\u041a\u0422\u0418\u0422\u041e\u0412\u0418\u0425 \u0413\u041b\u0418\u041d STUDY OF PROCESSES OF CLEANING OF OIL PRODUCTS ACCORDING TO ASSISTED SMECTITE CLAYS \u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 82-90. \u041d\u043e\u043c\u0435\u0440: \u21161, 2019 (269) \u0410\u0432\u0442\u043e\u0440\u0438: \u0410.\u042f. \u0413\u0410\u041d\u0417\u042e\u041a, \u0414.\u041c. \u0412\u0418\u0428\u041d\u0415\u0412\u0421\u042c\u041a\u0410, \u041d.\u041b. \u041f\u041e\u0425\u0418\u041b\u041e \u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442 \u041e.\u041f. \u0428\u0415\u041b\u0415\u0421\u0422\u042e\u041a, \u041e.\u041c. \u041c\u0406\u0429\u0423\u041a \u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0443\u043a\u043e\u0432\u043e-\u0434\u043e\u0441\u043b\u0456\u0434\u043d\u0438\u0439 \u0435\u043a\u0441\u043f\u0435\u0440\u0442\u043d\u043e-\u043a\u0440\u0438\u043c\u0456\u043d\u0430\u043b\u0456\u0441\u0442\u0438\u0447\u043d\u0438\u0439 \u0446\u0435\u043d\u0442\u0440 \u041c\u0412\u0421 \u0423\u043a\u0440\u0430\u0457\u043d\u0438 A.Y. GANZYUK,\u00a0 D.M. VISHNEVSKAYA, N.L. POHIULO Khmelnytskyi [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[21],"tags":[],"_links":{"self":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/2022"}],"collection":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=2022"}],"version-history":[{"count":4,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/2022\/revisions"}],"predecessor-version":[{"id":5734,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/2022\/revisions\/5734"}],"wp:attachment":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=2022"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=2022"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=2022"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}