{"id":7923,"date":"2021-08-31T18:54:19","date_gmt":"2021-08-31T15:54:19","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=7923"},"modified":"2021-09-29T15:09:03","modified_gmt":"2021-09-29T12:09:03","slug":"formuvannya-pokaznykiv-yakosti-shkir-riznyh-vydiv-shkiryanoyi-syrovyny-iz-vykorystannyam-montmorylonitu","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=7923","title":{"rendered":"\u0424\u043e\u0440\u043c\u0443\u0432\u0430\u043d\u043d\u044f \u043f\u043e\u043a\u0430\u0437\u043d\u0438\u043a\u0456\u0432 \u044f\u043a\u043e\u0441\u0442\u0456 \u0448\u043a\u0456\u0440 \u0440\u0456\u0437\u043d\u0438\u0445 \u0432\u0438\u0434\u0456\u0432 \u0448\u043a\u0456\u0440\u044f\u043d\u043e\u0457 \u0441\u0438\u0440\u043e\u0432\u0438\u043d\u0438 \u0456\u0437 \u0432\u0438\u043a\u043e\u0440\u0438\u0441\u0442\u0430\u043d\u043d\u044f\u043c \u043c\u043e\u043d\u0442\u043c\u043e\u0440\u0438\u043b\u043e\u043d\u0456\u0442\u0443"},"content":{"rendered":"<p><!--more--><\/p>\n<p style=\"text-align: center;\">\u0424\u041e\u0420\u041c\u0423\u0412\u0410\u041d\u041d\u042f \u041f\u041e\u041a\u0410\u0417\u041d\u0418\u041a\u0406\u0412 \u042f\u041a\u041e\u0421\u0422\u0406 \u0428\u041a\u0406\u0420 \u0420\u0406\u0417\u041d\u0418\u0425 \u0412\u0418\u0414\u0406\u0412 \u0428\u041a\u0406\u0420\u042f\u041d\u041e\u0407 \u0421\u0418\u0420\u041e\u0412\u0418\u041d\u0418 \u0406\u0417 \u0412\u0418\u041a\u041e\u0420\u0418\u0421\u0422\u0410\u041d\u041d\u042f\u041c \u041c\u041e\u041d\u0422\u041c\u041e\u0420\u0418\u041b\u041e\u041d\u0406\u0422\u0423<\/p>\n<p style=\"text-align: center;\">FORMATION OF LEATHER QUALITY INDICATORS OF DIFFERENT TYPES OF LEATHER RAW MATERIALS WITH THE USE OF MONTMORILONITE<\/p>\n<p><strong>\u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 136-142. \u041d\u043e\u043c\u0435\u0440: \u21163, 2021 (297)<\/strong> <a href=\"http:\/\/journals.khnu.km.ua\/vestnik\/wp-content\/uploads\/2021\/08\/23-2.pdf\"> <img loading=\"lazy\" class=\"size-full wp-image-69 alignnone\" src=\"http:\/\/journals.khnu.km.ua\/vestnik\/wp-content\/uploads\/2021\/01\/pdf.png\" alt=\"\" width=\"76\" height=\"32\" \/><\/a><br \/>\n<strong>\u0410\u0432\u0442\u043e\u0440\u0438:<\/strong><br \/>\n\u041c. \u041f. \u0416\u0410\u041b\u0414\u0410\u041a, \u041d. \u0412. \u041c\u0415\u0420\u0415\u0416\u041a\u041e, \u0412. \u0410. \u041e\u0421\u0418\u041a\u0410<br \/>\n\u041a\u0438\u0457\u0432\u0441\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0442\u043e\u0440\u0433\u043e\u0432\u0435\u043b\u044c\u043d\u043e-\u0435\u043a\u043e\u043d\u043e\u043c\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442<br \/>\nMARYNA P. ZHALDAK, NINA V. MEREZHKO, VICTOR A. OSYKA<br \/>\nKyiv National University of Trade and Economics<br \/>\n<strong>DOI:<\/strong>\u00a0<a href=\"https:\/\/www.doi.org\/10.31891\/2307-5732-2021-297-3-136-142\">https:\/\/www.doi.org\/10.31891\/2307-5732-2021-297-3-136-142<\/a><br \/>\n<strong>\u041d\u0430\u0434\u0456\u0439\u0448\u043b\u0430 \/ Paper received :\u00a0 <\/strong>18.05.2021 \u0440<br \/>\n<strong>\u041d\u0430\u0434\u0440\u0443\u043a\u043e\u0432\u0430\u043d\u0430 \/ Paper Printed : <\/strong>30.06.2021 \u0440<\/p>\n<p style=\"text-align: center;\"><strong>\u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443<\/strong><\/p>\n<p>\u0412 \u0440\u043e\u0431\u043e\u0442\u0456 \u043f\u0440\u043e\u0432\u0435\u0434\u0435\u043d\u043e \u0430\u043d\u0430\u043b\u0456\u0437 \u043f\u043e\u043a\u0430\u0437\u043d\u0438\u043a\u0456\u0432 \u044f\u043a\u043e\u0441\u0442\u0456 \u0448\u043a\u0456\u0440 \u0437 \u0440\u0456\u0437\u043d\u0438\u0445 \u0432\u0438\u0434\u0456\u0432 \u0441\u0438\u0440\u043e\u0432\u0438\u043d\u0438, \u0449\u043e \u043e\u0442\u0440\u0438\u043c\u0430\u043d\u0456 \u0456\u0437 \u0432\u0438\u043a\u043e\u0440\u0438\u0441\u0442\u0430\u043d\u043d\u044f\u043c \u0434\u0443\u0431\u043b\u0435\u043d\u043d\u044f \u0437\u0456 \u0437\u043c\u0435\u043d\u0448\u0435\u043d\u0438\u043c\u0438 \u0432\u0438\u0442\u0440\u0430\u0442\u0430\u043c\u0438 \u0441\u043f\u043e\u043b\u0443\u043a \u0445\u0440\u043e\u043c\u0443 \u0442\u0430 \u0441\u0443\u043c\u0456\u0449\u0435\u043d\u0438\u043c \u0437\u0430\u0441\u0442\u043e\u0441\u0443\u0432\u0430\u043d\u043d\u044f\u043c \u043c\u043e\u0434\u0438\u0444\u0456\u043a\u043e\u0432\u0430\u043d\u043e\u0433\u043e \u0441\u043f\u043e\u043b\u0443\u043a\u0430\u043c\u0438 \u0430\u043b\u044e\u043c\u0456\u043d\u0456\u044e \u043c\u043e\u043d\u0442\u043c\u043e\u0440\u0438\u043b\u043e\u043d\u0456\u0442\u0443. \u0414\u043e\u0432\u0435\u0434\u0435\u043d\u043e, \u0449\u043e \u0448\u043a\u0456\u0440\u0438 \u0437 \u0441\u0438\u0440\u043e\u0432\u0438\u043d\u0438 \u043a\u043e\u0437\u043b\u0438\u043d\u0438 \u0442\u0430 \u043e\u0432\u0447\u0438\u043d\u0438 \u043f\u043e\u0440\u0456\u0432\u043d\u044f\u043d\u043e \u0456\u0437 \u0432\u0435\u043b\u0438\u043a\u043e\u044e \u0440\u043e\u0433\u0430\u0442\u043e\u044e \u0445\u0443\u0434\u043e\u0431\u043e\u044e, \u0445\u0430\u0440\u0430\u043a\u0442\u0435\u0440\u0438\u0437\u0443\u044e\u0442\u044c\u0441\u044f \u043f\u0456\u0434\u0432\u0438\u0449\u0435\u043d\u0438\u043c\u0438 \u0432\u0438\u0445\u043e\u0434\u043e\u043c \u043f\u043b\u043e\u0449\u0456, \u0442\u043e\u0432\u0449\u0438\u043d\u0438, \u043e\u0431\u2019\u0454\u043c\u043d\u043e\u0433\u043e \u0432\u0438\u0445\u043e\u0434\u0443 \u0442\u0430 \u0440\u0456\u0432\u043d\u043e\u043c\u0456\u0440\u043d\u0456\u0441\u0442\u044e \u0444\u043e\u0440\u043c\u0443\u0432\u0430\u043d\u043d\u044f \u043f\u043e\u043a\u0430\u0437\u043d\u0438\u043a\u0456\u0432 \u044f\u043a\u043e\u0441\u0442\u0456 \u0443 \u0440\u0456\u0437\u043d\u0438\u0445 \u0442\u043e\u043f\u043e\u0433\u0440\u0430\u0444\u0456\u0447\u043d\u0438\u0445 \u0434\u0456\u043b\u044f\u043d\u043a\u0430\u0445.<br \/>\n<strong>\u041a\u043b\u044e\u0447\u043e\u0432\u0456 \u0441\u043b\u043e\u0432\u0430:<\/strong> \u0448\u043a\u0456\u0440\u044f\u043d\u0430 \u0441\u0438\u0440\u043e\u0432\u0438\u043d\u0430, \u043f\u043e\u043a\u0430\u0437\u043d\u0438\u043a\u0438 \u044f\u043a\u043e\u0441\u0442\u0456,\u0448\u043a\u0456\u0440\u0430 \u0434\u043b\u044f \u0432\u0435\u0440\u0445\u0443 \u0432\u0437\u0443\u0442\u0442\u044f, \u043c\u043e\u043d\u0442\u043c\u043e\u0440\u0438\u043b\u043e\u043d\u0456\u0442<\/p>\n<p style=\"text-align: center;\"><strong>\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n<p>The tanning process is important in stabilizing the collagen structure of the derma. \u0421hrome tanning is the traditional option. The basic chromium sulfate is used in the production of 80% of leather in use. A peculiarity of chromium tanning turns out to be an inefficient use of chromium compounds, since almost 40% of tannins remain in wastewater. Considering the disadvantages of using chromium compounds, scientific research on the replacement and use of rather eco-friendlier substances has been conducted for a long time.<br \/>\nOne of the directions of ecologization of leather manufacturing is the use of modified montmorillonite dispersions in various technological processes such as tanning, filling, dyeing, fat-liquoring, etc. Researches have been aimed at identifying the feasibility of making leather for the uppers of children&#8217;s shoes from different types of leather raw materials using modified dispersions of montmorillonite at the stage of tanning.<br \/>\nAccording to the technology of making leather, cattle (medium heifer), goat and sheep skins were used for the upper of the shoes.<br \/>\nThe analysis of leather quality indicators from different types of raw materials obtained with the use of chromefree tanning. It is proved that hides from raw materials of goats and sheepskins in comparison with cattle are characterized by increased yield area by 3.5-7.2 %, thickness by 0.8-2.6 %, volume yield by 4.5-6.1 % and uniformity of quality indicators in different topographic areas. The level of indicators of physical and mechanical, hygienic properties and chemical composition of leather of different types of raw materials is almost identical within the requirements of regulatory documents. It is advisable to use for children&#8217;s shoes leather from raw goat and sheepskin given the peculiarities of the manufacture of children&#8217;s shoes, dimensional characteristics of parts, requirements for dimensional stability and shape conservation.<br \/>\n<strong>Key words:<\/strong> leather raw materials, quality indicators, leather for shoe uppers, montmorillonite.<\/p>\n<p style=\"text-align: center;\"><strong>References<\/strong><\/p>\n<ol>\n<li>Sergeyev Y. The classification of microstructures of clay soils \/ [Y. Sergeyev, B. Grabowska-Olszewska, V.Osipov, Sokolov V. N] \/\/ Journal of Microscopy, 2011. \u2013 Vol. 20(3) \u2013 R. 237-260. doi: https:\/\/doi.org\/10.1111\/j.1365-2818.1980.tb04146.x<\/li>\n<li>Otroshko V. A. Vplyv polimerno-mineralnoi kompozytsii ta yii skladovykh na temperaturostiikist kolahenu \/V. A. Otroshko, O. R. Mokrousova, N. V. Merezhko\/\/ Visnyk KhNU, 2015. \u2013 \u21161(221). \u2013 S. 225-231.<\/li>\n<li>Mokrousova O. R. Mineralni napovniuvachi dlia shkir. Reolohichni vlastyvosti ta dyspersnist yikh vodnykh suspenzii \/ O. R. Mokrousova, V. N. Moraru \/\/ Visnyk KNUTD, 2010. \u2013 \u2116 4. \u2013 S. 256-264.<\/li>\n<li>Danylkovych A. Improvement of the filling and plasticization processes of forming multifunctional leather materials \/ A. Danylkovych, O. Mokrousova, A. Zhegotsky\/\/ EasternEuropean Journal of Enterprise Technologies, 2016.\u2013 Vol. 6(80), \u2013 R. 23\u201331. doi: https:\/\/doi.org\/10.15587\/1729-4061.2016.65488<\/li>\n<li>Otroshko V. A. Vzaiemodiia kolahenu dermy z mineralnymy ta polimernymy spolukamy \/V. A. Otroshko, O. R. Mokrousova, N. V. Merezhko\/\/ Tekhnolohichnyi audyt ta rezervy vyrobnytstva, 2016. \u2013 \u2116 2\/4 (28). \u2013 S. 48-54.<\/li>\n<li>Mokrousova O. R. Orhano-mineralnyi sklad na osnovi montmorylonitu ta lihnosulfonativ dlia dodubliuvannia-napovniuvannia shkirianoho napivfabrykatu \/Mokrousova Olena Romanivna\/\/ Visnyk KNUTD, 2008. \u2013 \u2116 6. \u2013 S. 67-73.<\/li>\n<li>Stadnik K. The usage of modified montmorillonite to enhance the quality of leather velour. \/ Stadnik K., Okhmat O., Mokrousova O. \/\/IOP Conference Series Materials Science and Engineering, 2019. \u2013 Vol. 500(1). \u2013 R. 1-6. doi: https:\/\/doi.org\/ 10.1088\/1757-899X\/500\/1\/012035<\/li>\n<li>Pidvyshchennia efektyvnosti ridynnoho ozdoblennia veliuru shliakhom zastosuvannia modyfikovanykh dyspersii montmorylonitu. Perspektyvni materialy ta innovatsiini tekhnolohii: biotekhnolohiia, prykladna khimiia ta ekolohiia : kolektyvna monohrafiia \/ [Okhmat O. A., Bondarieva A.O., Mokrousova O. R. ta in.]; za red. Mokrousova O. R. Kyiv : Svit uspikhu, 2020. \u2013 S. 305-313.<\/li>\n<li>Bao Y. Tanning mechanism of vinyl polymer\/montmorillonite nanocomposite tannage \/ Bao Y., Ma J., Zongsui Y. \/\/ Journal of the Society of Leather Technologists and Chemists, 2007. \u2013 Vol. 91. \u2013 P. 162-167.<\/li>\n<li>Bao Y. Preparation of acrilic resin\/montmorillonite nanocomposite for leather tanning agent \/ Bao Y., Ma J., Wangi Y.-L.\/\/ JALCA, 2009. \u2013 Vol. 104, \u2013 Issue 10. \u2013 P. 352\u2212358.<\/li>\n<li>Mokrousova O. Resources-saving Chromium Tanning of Leather with the Use of Modified Montmorillonite \/Mokrousova O., Danylkovich A., Palamar V. \/\/ Revista de chemie, 2015. Vol. 66. \u2116 3. R. 353-357.<\/li>\n<li>Danylkovych A. H. Tekhnolohiia i materialy vyrobnytstva shkiry: navch. pos. \/Danylkovych A. H., Mokrousova O. R., Okhmat O. A. \u2013 K. : Feniks, 2009. \u2013 580 s.<\/li>\n<li>Universalnyi dovidnyk vzuttievyka : navch. posib. \/ [V. P. Konoval, S. S. Harkavenko ta in.]; 2-e vyd. Kyiv : Libra, 2006. \u2013 719 c.<\/li>\n<li>Zhaldak M. Rreparation and application of modified montmorillonite dispersion for chrome-less tanning of leather \/M. Zhaldak, O. Mokrousova\/\/ Revista de Pielarie Incaltaminte, 2020. \u2013 Vol. 3(20). \u2013 P. 287-300.<\/li>\n<li>Matetskene N. Y. Vlyianye oryentatsyy voloknystoi struktur\u044b kozhy na ko\u044dfytsyent neravnomernosty udlynenyi. Kozhevenno-obuvnaia prom\u044bshlennost \/Matetskene N. Y., Levchenko P. Y., Stashevychus A. Yu. \u2013 M., 1973. \u2013 \u2116 4. \u2013 S. 50-52.<\/li>\n<li>Dumnov V. S. Yssledovanye usadky kollahenov\u044bkh volokon. Kozhevenno-obuvnaia prom\u044bshlennost \/ V. S.Dumnov, Yu. O.Trunyn. \u2013 M., 1977. \u2013 \u2116 9. \u2013 S. 48-50.<\/li>\n<li>Shkira dlia verkhu vzuttia. Tekhnichni umovy: DSTU 2726-94 (HOST 939-94). \u2013 [Chynnyi vid 01-01-1996]. \u2013 Kyiv: Derzhspozhyvstandart Ukrainy, 1996. \u2013 19 s. \u2013 (Natsionalnyi standart Ukrainy).<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[51],"tags":[],"_links":{"self":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/7923"}],"collection":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=7923"}],"version-history":[{"count":5,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/7923\/revisions"}],"predecessor-version":[{"id":8310,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/7923\/revisions\/8310"}],"wp:attachment":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=7923"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=7923"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=7923"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}