{"id":8473,"date":"2021-10-25T14:57:35","date_gmt":"2021-10-25T11:57:35","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=8473"},"modified":"2021-11-22T13:08:51","modified_gmt":"2021-11-22T11:08:51","slug":"modelyuvannya-pokaznykiv-yakosti-pokryttya-shkir","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=8473","title":{"rendered":"\u041c\u043e\u0434\u0435\u043b\u044e\u0432\u0430\u043d\u043d\u044f \u043f\u043e\u043a\u0430\u0437\u043d\u0438\u043a\u0456\u0432 \u044f\u043a\u043e\u0441\u0442\u0456 \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f \u0448\u043a\u0456\u0440"},"content":{"rendered":"

<\/p>\n

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MODELING OF QUALITY INDICATORS OF THE LEATHER COATING<\/p>\n

\u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 115-122. \u041d\u043e\u043c\u0435\u0440: \u21164, 2021 (299)<\/strong> \"\"<\/a>
\n\u0410\u0432\u0442\u043e\u0440\u0438:<\/strong>
\n\u0410.\u041e. \u0411\u041e\u041d\u0414\u0410\u0420\u0404\u0412\u0410
\n\u041a\u0438\u0457\u0432\u0441\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0442\u043e\u0440\u0433\u043e\u0432\u0435\u043b\u044c\u043d\u043e-\u0435\u043a\u043e\u043d\u043e\u043c\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442
\nORCID ID: 0000-0002-3241-2726
\ne-mail: a.bondarieva@knute.edu.ua
\n\u0415.\u0404. \u041a\u0410\u0421\u042c\u042f\u041d
\n\u041a\u0438\u0457\u0432\u0441\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442 \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0439 \u0442\u0430 \u0434\u0438\u0437\u0430\u0439\u043d\u0443
\nORCID ID: 0000-0002-9540-2824
\ne-mail: kee2@ukr.net
\n\u041e.\u0420. \u041c\u041e\u041a\u0420\u041e\u0423\u0421\u041e\u0412\u0410
\n\u041a\u0438\u0457\u0432\u0441\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0442\u043e\u0440\u0433\u043e\u0432\u0435\u043b\u044c\u043d\u043e-\u0435\u043a\u043e\u043d\u043e\u043c\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442
\nORCID ID: 0000-0003-1943-8048
\ne-mail: olenamokrousova@gmail.com
\n\u0410nna \u041e. BONDARYEVA
\nKyiv National University Of Trade And Economics
\nEduard E. KASYAN
\nKyiv National University of Technologies And Design
\n\u041elena R. MOKROUSOVA
\nKyiv National University Of Trade And Economics
\nDOI:<\/strong> https:\/\/www.doi.org\/10.31891\/2307-5732-2021-299-4-115-122<\/a>
\n\u0420\u0435\u0446\u0435\u043d\u0437\u0456\u044f\/Peer review :<\/strong> 08.08.2021 \u0440.
\n\u041d\u0430\u0434\u0440\u0443\u043a\u043e\u0432\u0430\u043d\u0430\/Printed :<\/strong> 26.08.2021 \u0440.<\/p>\n

\u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443<\/strong><\/p>\n

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\n\u041a\u043b\u044e\u0447\u043e\u0432\u0456 \u0441\u043b\u043e\u0432\u0430:<\/strong> \u043e\u0437\u0434\u043e\u0431\u043b\u0435\u043d\u043d\u044f, \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f, \u0448\u043a\u0456\u0440\u0430, \u043c\u043e\u0434\u0435\u043b\u044e\u0432\u0430\u043d\u043d\u044f, \u043e\u043f\u0442\u0438\u043c\u0456\u0437\u0430\u0446\u0456\u044f, \u043f\u043b\u0456\u0432\u043a\u043e\u0443\u0442\u0432\u043e\u0440\u044e\u0432\u0430\u0447, \u043f\u0456\u0433\u043c\u0435\u043d\u0442.<\/p>\n

\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n

The article is devoted to modeling the quality of leather coatings by optimizing the composition of the coating composition based on polymer film formers of different chemical nature and pigment material. Finishing coating affects the quality of the leather coating and regulates the physico-chemical, physico-mechanical and hygienic parameters of the leather semi-finished product. The quality of the leather coating is assessed by a lot of indicators. Quantitative indicators of physicochemical, physico-mechanical and hygienic properties characterize the behavior of the coating during operation. The aim of the work is to model the quality indicators of the leather coating by optimizing the composition of the coating composition obtained using pigment materials based on colored modified dispersions of montmorillonite and polymer film formers of different chemical nature. The influence of components of covering compositions on physical-mechanical and operational indicators of a covering is investigated in the work. Mathematical models were obtained using D-optimal simplex lattice plans of the experiment. Using mathematical models, the influence of individual components of the coating composition and their ratio on the quality of the leather coating is described. By multicriteria optimization of the generalized desirability function and the method of fair compromise, the optimal (rational) ratios of the components of the coating composition are obtained, which give the leather finishing coating the necessary quality indicators. The obtained experimental indicators of the properties of the leather coating are completely correlated with the indicators calculated by modeling. This confirms the reliability of the simulation results and indicate the high quality of the studied coating on the leather.
\nKeywords:<\/strong> finishing, coating, leather, modeling, optimization, film former, pigment<\/p>\n

References<\/strong><\/p>\n

    \n
  1. Arthur A. Tracton. Coatings technology Handbook. Taylor and Francis Group. 2006. 829 p.<\/li>\n
  2. Arthur A. Tracton. Coatings Materials and Surface Coatings. CRC Press.Taylor and Francis Group. New York. 2007. 464 p.<\/li>\n
  3. Zurabyan K. M., Bajdakova L. I. Otdelka kozh \/ Zurabyan K. M., Bajdakova L. I. \u2013 M. : Legk. i pish. prom-st, 1984. \u2013 184 s.<\/li>\n
  4. Ekolohichno oriientovani tekhnolohii vyrobnytstva shkirianykh ta khutrovykh materialiv dlia stvorennia konkurentospromozhnykh tovariv : monohrafiia : v 2 ch. Ch. 1 \/ Ekolohichno oriientovani tekhnolohii vyrobnytstva shkirianykh ta khutrovykh materialiv \/ [Danylkovych A. H., Lishchuk V. I., Plavan V. P., Kasian E. Ye., Zhyhotskyi O. H.] ; za red. A. H. Danylkovycha. \u2013 K. : Feniks, 2011. \u2013 438 s.<\/li>\n
  5. Kasian E. Ye. Fizyko-khimiia polimernykh plivkoutvoriuvachiv dlia ozdoblennia shkiry : [navch. posib.] \/ Kasian E. Ye. \u2013 Kyiv : Osvita Ukrainy, 2019. \u2013 178 s.<\/li>\n
  6. Winter C., Borges Agustini C., Elizabeth M., Schultz R., Gutterres M. Influence of pigment addition on the properties of Polymer films for leather finishing. J. Soc. Leather. Technol. Chem. 2017. Vol. 101. \u2116 2. P. 78\u201385.<\/li>\n
  7. Osgood m. J. Pigments in modern leather finishing. J. Soc. Leather. Technol. Chem. 1990. Vol. 74. \u2116 1. P. 1\u20136.<\/li>\n
  8. Bondarieva O.A. Rozrobka ta vykorystannia hibrydnykh pihmentiv u pokryvnomu ozdoblenni shkir \/ O.A. Bondarieva, O.R.\u00a0Mokrousova, O.A. Okhmat \/\/ Visnyk Khmelnytskoho natsionalnoho universytetu. Tekhnichni nauky. \u2013 2020. \u2013 \u2116 2 (283). \u2013 S. 26\u201336.<\/li>\n
  9. Bondaryeva Anna, Mokrousova Olena, Okhmat Olena. Hybrid pigments based on montmorillonite and anionic dyes for leather finishing. Solid State Phenomena. 2021. Vol. 320, pp. 198\u2013203.<\/li>\n
  10. Bondarieva A.O., Mokrousova O.R., Okhmat O.A. Sposib otrymannia pihmentnoho kontsentratu dlia ozdoblennia shkir. Patent UA \u2116 144635 Ukraina. opubl. 12.10.2020, \u00abPromyslova vlasnist\u00bb, biul. \u2116 19\/2020.<\/li>\n
  11. Bondarieva A.O. Formuvannia fizyko-mekhanichnykh vlastyvostei polimerno-mineralnoho pokryttia dlia ozdoblennia shkir \/ A.O.\u00a0Bondarieva, O.R. Mokrousova Tovary i rynky. \u2013 2020. \u2013 \u2116 2. \u2013 S. 97\u2013109.<\/li>\n
  12. Spravochnik kozhevnika: otdelka. Kontrol proizvodstva \/ [pod red. N. A. Balberovoj]. \u2013 M. : Legprombytizdat, 1987. \u2013 256 s.<\/li>\n
  13. Danylkovych A.H. Tekhnolohiia i materialy vyrobnytstva shkiry : navchalnyi posibnyk \/ Danylkovych A.H., Mokrousova O.R., Okhmat O.A. \u2013 K. : Feniks, 2009. \u2013 578 s.<\/li>\n
  14. Danylkovych A. H. Praktykum z khimii ta tekhnolohii shkiry ta khutra : navch. posibnyk \/ Danylkovych A. H. \u2013 K. : Feniks, 2006. \u2013 338 s.<\/li>\n
  15. Zedginidze I.G. Planirovanie eksperimenta dlya issledovaniya mnogokomponentnyh sistem \/ Zedginidze I.G. \u2013 M. : Nauka, 1976. \u2013 390 s.<\/li>\n
  16. Ahnazarova S.L. Metody optimizacii eksperimenta v himicheskoj tehnologii \/ Ahnazarova S.L., Kafarov V.V. \u2013 M. : Vysshaya shkola, 1985. \u2013 327 s.<\/li>\n
  17. Bondar A.G. Planirovanie eksperimenta pri optimizacii processov himicheskoj tehnologii \/ Bondar A.G., Statyuha G.A., Potyazhenko I. A. \u2013 K. : Visha shkola, 1980. \u2013 264 s.<\/li>\n<\/ol>\n

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