{"id":8509,"date":"2021-10-25T15:05:38","date_gmt":"2021-10-25T12:05:38","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=8509"},"modified":"2021-11-22T13:01:56","modified_gmt":"2021-11-22T11:01:56","slug":"aktualni-pytannya-monitoryngu-vmistu-hlorytiv-ta-hlorativ-u-pytnij-vodi-pislya-znezarazhuvannya-okysnyuvachamy","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=8509","title":{"rendered":"\u0410\u043a\u0442\u0443\u0430\u043b\u044c\u043d\u0456 \u043f\u0438\u0442\u0430\u043d\u043d\u044f \u043c\u043e\u043d\u0456\u0442\u043e\u0440\u0438\u043d\u0433\u0443 \u0432\u043c\u0456\u0441\u0442\u0443 \u0445\u043b\u043e\u0440\u0438\u0442\u0456\u0432 \u0442\u0430 \u0445\u043b\u043e\u0440\u0430\u0442\u0456\u0432 \u0443 \u043f\u0438\u0442\u043d\u0456\u0439 \u0432\u043e\u0434\u0456  \u043f\u0456\u0441\u043b\u044f \u0437\u043d\u0435\u0437\u0430\u0440\u0430\u0436\u0443\u0432\u0430\u043d\u043d\u044f \u043e\u043a\u0438\u0441\u043d\u044e\u0432\u0430\u0447\u0430\u043c\u0438"},"content":{"rendered":"<p><!--more--><\/p>\n<p style=\"text-align: center;\">\u0410\u041a\u0422\u0423\u0410\u041b\u042c\u041d\u0406 \u041f\u0418\u0422\u0410\u041d\u041d\u042f \u041c\u041e\u041d\u0406\u0422\u041e\u0420\u0418\u041d\u0413\u0423 \u0412\u041c\u0406\u0421\u0422\u0423 \u0425\u041b\u041e\u0420\u0418\u0422\u0406\u0412 \u0422\u0410 \u0425\u041b\u041e\u0420\u0410\u0422\u0406\u0412 \u0423 \u041f\u0418\u0422\u041d\u0406\u0419 \u0412\u041e\u0414\u0406\u00a0 \u041f\u0406\u0421\u041b\u042f \u0417\u041d\u0415\u0417\u0410\u0420\u0410\u0416\u0423\u0412\u0410\u041d\u041d\u042f \u041e\u041a\u0418\u0421\u041d\u042e\u0412\u0410\u0427\u0410\u041c\u0418<br \/>\nCURRENT ISSUES OF MONITORING THE CHLORITE AND CHLORITE CONTENT IN DRINKING WATER AFTER OXIDATION DISINFECTION<\/p>\n<p><strong>\u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: 7-10. \u041d\u043e\u043c\u0435\u0440: \u21164, 2021 (299)<\/strong> <a href=\"http:\/\/journals.khnu.km.ua\/vestnik\/wp-content\/uploads\/2021\/10\/299-text_2021_4_t-7-10.pdf\"> <img loading=\"lazy\" class=\"size-full wp-image-69 alignnone\" src=\"http:\/\/journals.khnu.km.ua\/vestnik\/wp-content\/uploads\/2021\/01\/pdf.png\" alt=\"\" width=\"76\" height=\"32\" \/><\/a><br \/>\n<strong>\u0410\u0432\u0442\u043e\u0440\u0438:<\/strong><br \/>\n\u0410.\u0412. \u041c\u041e\u041a\u0406\u0404\u041d\u041a\u041e<br \/>\n\u041e\u0434\u0435\u0441\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u043c\u0435\u0434\u0438\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442<br \/>\nORCID ID: <strong>0000-0002-4491-001<\/strong><strong>X<\/strong><strong><br \/>\n<\/strong>e-mail: mokienkoav56@gmail.com<br \/>\n\u041b.\u041c. \u0421\u041f\u0410\u0421\u042c\u041e\u041d\u041e\u0412\u0410<br \/>\n\u041d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0442\u0435\u0445\u043d\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442 \u0423\u043a\u0440\u0430\u0457\u043d\u0438 \u00ab\u041a\u0438\u0457\u0432\u0441\u044c\u043a\u0438\u0439 \u043f\u043e\u043b\u0456\u0442\u0435\u0445\u043d\u0456\u0447\u043d\u0438\u0439 \u0456\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0456\u043c\u0435\u043d\u0456 \u0406\u0433\u043e\u0440\u044f \u0421\u0456\u043a\u043e\u0440\u0441\u044c\u043a\u043e\u0433\u043e\u00bb<br \/>\ne-mail: <a href=\"mailto:lar_spas@yahoo.com\">lar_spas@yahoo.com<\/a><br \/>\n\u041e. \u042e. \u0411\u041e\u041d\u0414\u0410\u0420\u0427\u0423\u041a<br \/>\n\u041d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0442\u0435\u0445\u043d\u0456\u0447\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442 \u0423\u043a\u0440\u0430\u0457\u043d\u0438 \u00ab\u041a\u0438\u0457\u0432\u0441\u044c\u043a\u0438\u0439 \u043f\u043e\u043b\u0456\u0442\u0435\u0445\u043d\u0456\u0447\u043d\u0438\u0439 \u0456\u043d\u0441\u0442\u0438\u0442\u0443\u0442 \u0456\u043c\u0435\u043d\u0456 \u0406\u0433\u043e\u0440\u044f \u0421\u0456\u043a\u043e\u0440\u0441\u044c\u043a\u043e\u0433\u043e\u00bb<br \/>\ne-mail: \u00a0\u00a0\u00a0 Bondarchukau@gmail.com<br \/>\nA.V. MOKIENKO<br \/>\nOdessa National Medical University<br \/>\nORCID ID: 0000-0002-4491-001X<br \/>\ne-mail: mokienkoav56@gmail.com<br \/>\nL.M. SPASIONOVA<br \/>\nNational Technical University of Ukraine &#8220;Igor Sikorsky Kyiv Polytechnic Institute&#8221;<br \/>\nORCID ID: 0000-0002-7562-7241<br \/>\ne-mail: lar_spas@yahoo.com<br \/>\nYu. BONDARCHUK<br \/>\nNational Technical University of Ukraine &#8220;Igor Sikorsky Kyiv Polytechnic Institute&#8221;<br \/>\nORCID ID: &#8211;<br \/>\ne-mail: Bondarchukau@gmail.com<br \/>\n<strong>DOI:<\/strong> <a href=\"https:\/\/www.doi.org\/10.31891\/2307-5732-2021-299-4-7-10\">https:\/\/www.doi.org\/10.31891\/2307-5732-2021-299-4-7-10<\/a><br \/>\n<strong>\u0420\u0435\u0446\u0435\u043d\u0437\u0456\u044f\/Peer review :<\/strong> 08.08.2021 \u0440.<br \/>\n<strong>\u041d\u0430\u0434\u0440\u0443\u043a\u043e\u0432\u0430\u043d\u0430\/Printed :<\/strong> 26.08.2021 \u0440.<\/p>\n<p style=\"text-align: center;\"><strong>\u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443<\/strong><\/p>\n<p>\u0412 \u0440\u043e\u0431\u043e\u0442\u0456 \u043d\u0430\u0432\u0435\u0434\u0435\u043d\u043e \u0440\u0435\u0437\u0443\u043b\u044c\u0442\u0430\u0442\u0438 \u0443\u0437\u0430\u0433\u0430\u043b\u044c\u043d\u0435\u043d\u043d\u044f \u0434\u0430\u043d\u0438\u0445 \u0449\u043e\u0434\u043e \u0443\u0442\u0432\u043e\u0440\u0435\u043d\u043d\u044f \u0445\u043b\u043e\u0440\u0438\u0442\u0456\u0432 \u0442\u0430 \u0445\u043b\u043e\u0440\u0430\u0442\u0456\u0432 \u0443 \u0432\u043e\u0434\u0456 \u0432\u043d\u0430\u0441\u043b\u0456\u0434\u043e\u043a \u0437\u043d\u0435\u0437\u0430\u0440\u0430\u0436\u0443\u0432\u0430\u043d\u043d\u044f \u043e\u043a\u0438\u0441\u043d\u044e\u0432\u0430\u0447\u0430\u043c\u0438 \u0442\u0430 \u043f\u0440\u0435\u0434\u0441\u0442\u0430\u0432\u043b\u0435\u043d\u043e \u043d\u0430\u043f\u0440\u044f\u043c\u043a\u0438 \u0434\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u044c \u0449\u043e\u0434\u043e \u0440\u043e\u0437\u0440\u043e\u0431\u043a\u0438\u00a0 \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0447\u043d\u0438\u0445 \u0437\u0430\u0441\u0430\u0434 \u0437 \u043c\u0456\u043d\u0456\u043c\u0456\u0437\u0430\u0446\u0456\u0457 \u0432\u043c\u0456\u0441\u0442\u0443 \u0446\u0438\u0445 \u043f\u043e\u0431\u0456\u0447\u043d\u0438\u0445 \u043f\u0440\u043e\u0434\u0443\u043a\u0442\u0456\u0432 \u0443 \u043f\u0438\u0442\u043d\u0456\u0439 \u0432\u043e\u0434\u0456.<br \/>\n<strong>\u041a\u043b\u044e\u0447\u043e\u0432\u0456 \u0441\u043b\u043e\u0432\u0430:<\/strong> \u043f\u0438\u0442\u043d\u0430 \u0432\u043e\u0434\u0430, \u0437\u043d\u0435\u0437\u0430\u0440\u0430\u0436\u0443\u0432\u0430\u043d\u043d\u044f, \u043e\u043a\u0438\u0441\u043d\u044e\u0432\u0430\u0447\u0456, \u0445\u043b\u043e\u0440\u0438\u0442\u0438, \u0445\u043b\u043e\u0440\u0430\u0442\u0438.<\/p>\n<p style=\"text-align: center;\"><strong>\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n<p>The use of oxidants (chlorine, chlorine dioxide and ozone) is a priority way of safe water supply. However, their use involves control of the formation, determination and normalization of chlorites and chlorates as by-products of disinfection. The aim of the work was to characterize the topical issues of monitoring the content of chlorites and chlorates in drinking water after disinfection with oxidants. Research methods included bibliometric and analytical. The results are as follows. The analysis of foreign and domestic normative documents testifies to the need to harmonize the current DSanPiN 2.2.4-171-10 &#8220;Hygienic requirements for drinking water suitable for human consumption&#8221; regarding the standardization of chlorites and chlorates in accordance with international requirements. It should be noted that these values, namely the normative values \u200b\u200bfor chlorites and chlorates at the level of 0.7 and 0.7 mg \/ l, respectively, were included in the latest version of the above-mentioned normative document DSanPiN 2.2.4-171-20. An analysis of the experience gained in Europe (European federation of national associations of water services) shows that the main source of chlorite and chlorate formation is not chlorine dioxide, as previously thought, but sodium hypochlorite. According to the WHO, chlorate is a typical by-product of disinfection in the treatment of water with oxidants (sodium hypochlorite, chloramines, chlorine dioxide, ozone). Currently, research on the development of technological principles for minimizing the content of chlorites and chlorates as by-products of water disinfection by oxidants in Ukraine has not been conducted. The above necessitates the implementation of the following tasks: generalization of research results of chlorite content in drinking water from centralized drinking water supply systems, where chlorine dioxide is used; development, testing and implementation of the method of determination of chlorates in drinking water; determination of the content of chlorites and chlorates in the finished sodium hypochlorite, which is supplied to water utilities, depending on the shelf life; monitoring the content of chlorites and chlorates in drinking water of settlements where sodium hypochlorite is used in the process of water treatment; determination of chlorate content in chlorinated tap water after its treatment with ozone; substantiation of optimal modes of water treatment with oxidants to minimize the content of chlorites and chlorates in drinking water from the water distribution network; development of technological principles for minimizing the content of chlorites and chlorates in drinking water after disinfection with oxidants.<br \/>\n<strong>Key words:<\/strong> drinking water, disinfection, oxidizers, chlorites, chlorates.<\/p>\n<p style=\"text-align: center;\"><strong>References<\/strong><\/p>\n<ol>\n<li>Prokopov V. O. Pitna voda Ukra\u0457ni: mediko-ekolog\u0456chn\u0456 ta san\u0456tarno-g\u0456g\u0456\u0454n\u0456chn\u0456 aspekti \/ za red. A. M. Serdjuka. Ki\u0457v : VSV \u00abMedicina\u00bb 2016. 400 s.<\/li>\n<li>Mokienko A.V., Petrenko N.F., Gozhenko A.I. Obezzarazhivanie vody. Gigienicheskie i mediko-jekologicheskie aspekty. T. 1. Hlor i ego soedinenija. TJeS, 2011. 484 s.<\/li>\n<li>Mokienko A.V., Petrenko N.F., Gozhenko A.I. Obezzarazhivanie vody. Gigienicheskie i mediko-jekologicheskie aspekty. T. 2. Dioksid hlora. Odessa. TJeS, 2012. 604 s.<\/li>\n<li>Mokienko A.V., Petrenko N.F., Gozhenko A.I. Obezzarazhivanie vody. Gigienicheskie i mediko-jekologicheskie aspekty. T. 3. Ozon. Fen\u0456ks. 2017. 322 s.<\/li>\n<li>Mokienko A.V. Obezzarazhivanie vody. Gigienicheskie i mediko &#8211; jekologicheskie aspekty. Tom 4. Ul&#8217;trafioletovoe obluchenie i kombinirovannye metody. Odessa. Fen\u0456ks. 2020. 378 s.<\/li>\n<li>Mokienko A.V. Dioksid hlora: primenenie v tehnologijah vodopodgotovki 2-e izd. pererab i dop. Odessa : \u00abFen\u0456ks\u00bb, 2021. 336 s.<\/li>\n<li>Pro zatverdzhennja Derzhavnih san\u0456tarnih norm ta pravil &#8220;G\u0456g\u0456\u0454n\u0456chn\u0456 vimogi do vodi pitno\u0457, priznacheno\u0457 dlja spozhivannja ljudinoju&#8221; 2.2.4-171\u201310. Nakaz M\u0456n\u0456sterstva ohoroni zdorov&#8217;ja Ukra\u0457ni v\u0456d 12 travnja 2010 roku N 400. Zare\u0454strovano v M\u0456n\u0456sterstv\u0456 justic\u0456\u0457 Ukra\u0457ni 1 lipnja 2010 r. za N 452\/17747. Rezhim dostupu: https:\/\/zakon.rada.gov.ua\/laws\/show\/z0452-10#Text<\/li>\n<li>Guidelines for drinking water quality: fourth edition incorporating the first addendum. World Health Organisation. Licence CC BY-NC-SA 3.0 IGO 2017. 631 p.<\/li>\n<li>Directive (EU) 2020\/2184 of the European parliament and of the council of 16 December 2020 on the quality of water intended for human consumption (recast). Rezhim dostupu: https:\/\/eur-lex.europa.eu\/legal-content\/EN\/TXT\/PDF\/?uri=CELEX:32020L2184&amp;from=ES.<\/li>\n<li>Siddiqui M. S. Chlorine-ozone interactions: Formation of chlorate M. S. Siddiqui \/\/ Water Research. \u2013 1996. \u2013 V. 30, N 9.\u00a0 \u2013 P. 2160\u00a0 \u2013 2170.<\/li>\n<li>Asami M. Bromate, chlorate, chlorite and perchlorate in sodium hypochlorite solution used in water supply \/ M. Asami, K. Kosaka, S. Kunikane \/\/ Journal of Water Supply: Research and Technology\u2014AQUA. \u2013 2009. \u2013 V. 58, N 2. \u2013 P. 107 \u2013 115<\/li>\n<li>WHO Chlorite and chlorate in drinking-water. Background document for preparation of WHO Guidelines for drinking-water quality. Geneva, World Health Organization (WHO\/SDE\/WSH\/03.04\/86) . \u2013 2003.<\/li>\n<li>EurEau (European federation of national associations of water services). 2018. Rezhim dostupu: https:\/\/www.eureau.org\/resources\/position-papers\/3012-drinking-water-directive-plenary-vote-eureau-explanatory-memorandum-1\/file<\/li>\n<li>Mokienko A. V. Jekologo-gigienicheskie osnovy bezopasnosti vody, obezzarazhennoj dioksidom hlora. Dis. &#8230; d. med. n.:\u00a0 02.01\u00a0 GU\u00abInstitut gigieny i medicinskoj jekologii\u00a0 im. A.N. Marzeeva AMN Ukrainy\u00bb. K.. 2009. 348 s.<\/li>\n<li>Fomin G.S., Fomina O.N. Pit&#8217;evaja i mineral&#8217;naja voda. Trebovanija mirovyh i evropejskih standartov k kachestvu i bezopasnosti. Moskva:\u201cProtektor\u201d. 320 s.<\/li>\n<li>Subchronic toxicity of sodium chlorite in the rat. M. Harrington et al. Jour. Amer. Coll. Toxicol. 1995. V 14, N 1. P. 21 \u2013 28.<\/li>\n<li>Aieta E.M., Roberts P.V., Hernandez M. Determination of Chlorine Dioxide, Chlorine, Chlorite and Chlorate in Water. J.AWWA. 1984. V.76, \u2116 7. P. 64 \u2013 74.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[52],"tags":[],"_links":{"self":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/8509"}],"collection":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=8509"}],"version-history":[{"count":6,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/8509\/revisions"}],"predecessor-version":[{"id":9483,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/8509\/revisions\/9483"}],"wp:attachment":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=8509"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=8509"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=8509"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}