{"id":9885,"date":"2021-12-14T19:45:58","date_gmt":"2021-12-14T17:45:58","guid":{"rendered":"http:\/\/journals.khnu.km.ua\/vestnik\/?p=9885"},"modified":"2022-03-15T10:45:27","modified_gmt":"2022-03-15T08:45:27","slug":"vplyv-skladu-i-tehnologichnyh-faktoriv-na-adgezijnu-micznist-ftoroplastovyh-pokryttiv-do-metalevyh-poverhon","status":"publish","type":"post","link":"https:\/\/journals.khnu.km.ua\/vestnik\/?p=9885","title":{"rendered":"\u0412\u043f\u043b\u0438\u0432 \u0441\u043a\u043b\u0430\u0434\u0443 \u0456 \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0447\u043d\u0438\u0445 \u0444\u0430\u043a\u0442\u043e\u0440\u0456\u0432 \u043d\u0430 \u0430\u0434\u0433\u0435\u0437\u0456\u0439\u043d\u0443 \u043c\u0456\u0446\u043d\u0456\u0441\u0442\u044c \u0444\u0442\u043e\u0440\u043e\u043f\u043b\u0430\u0441\u0442\u043e\u0432\u0438\u0445 \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u0456\u0432 \u0434\u043e \u043c\u0435\u0442\u0430\u043b\u0435\u0432\u0438\u0445 \u043f\u043e\u0432\u0435\u0440\u0445\u043e\u043d\u044c"},"content":{"rendered":"<p><!--more--><\/p>\n<p style=\"text-align: center;\">\u0412\u041f\u041b\u0418\u0412 \u0421\u041a\u041b\u0410\u0414\u0423 \u0406 \u0422\u0415\u0425\u041d\u041e\u041b\u041e\u0413\u0406\u0427\u041d\u0418\u0425 \u0424\u0410\u041a\u0422\u041e\u0420\u0406\u0412 \u041d\u0410 \u0410\u0414\u0413\u0415\u0417\u0406\u0419\u041d\u0423 \u041c\u0406\u0426\u041d\u0406\u0421\u0422\u042c \u0424\u0422\u041e\u0420\u041e\u041f\u041b\u0410\u0421\u0422\u041e\u0412\u0418\u0425 \u041f\u041e\u041a\u0420\u0418\u0422\u0422\u0406\u0412 \u0414\u041e \u041c\u0415\u0422\u0410\u041b\u0415\u0412\u0418\u0425 \u041f\u041e\u0412\u0415\u0420\u0425\u041e\u041d\u042c<\/p>\n<p style=\"text-align: center;\">THE INFLUENCE OF COMPOSITION AND TECHNOLOGICAL FACTORS ON ADHESION STRENGTH OF FLUOROPLASTICS COATINGS TO METAL SURFACES<\/p>\n<p><strong>\u0421\u0442\u043e\u0440\u0456\u043d\u043a\u0438: <\/strong><strong>45-51<\/strong><strong>. \u041d\u043e\u043c\u0435\u0440: \u21165, 2021 (301)<\/strong> <a href=\"http:\/\/journals.khnu.km.ua\/vestnik\/wp-content\/uploads\/2021\/12\/301-text_2021_5_t-45-51.pdf\"> <img loading=\"lazy\" class=\"size-full wp-image-69 alignnone\" src=\"http:\/\/journals.khnu.km.ua\/vestnik\/wp-content\/uploads\/2021\/01\/pdf.png\" alt=\"\" width=\"76\" height=\"32\" \/><\/a><br \/>\n<strong>\u00a0<\/strong><strong>\u0410\u0432\u0442\u043e\u0440\u0438:<\/strong><br \/>\n\u041e\u041b\u0415\u041a\u0421\u0410\u041d\u0414\u0420\u0415\u041d\u041a\u041e \u0412. \u041f.<br \/>\n\u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442<br \/>\nORCID ID: 0000-0002-2404-2104<br \/>\n\u0435-mail: <a href=\"mailto:oleksandrenko_vp@ukr.net\">oleksandrenko_vp@ukr.net<\/a><br \/>\n\u0421\u0412\u0406\u0414\u0415\u0420\u0421\u042c\u041a\u0418\u0419 \u0412. \u041f.<br \/>\n\u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442<br \/>\nORCID ID: \u00a00000-0003-4816-6977<br \/>\n\u0435-mail: <a href=\"mailto:svidersky.vladyslav@gmail.com\">svidersky.vladyslav@gmail.com<\/a><br \/>\n\u041a\u0418\u0420\u0418\u0427\u0415\u041d\u041a\u041e \u041b. \u041c.<br \/>\n\u0425\u043c\u0435\u043b\u044c\u043d\u0438\u0446\u044c\u043a\u0438\u0439 \u043d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442<br \/>\nORCID ID: \u00a00000-0001-6382-8911<br \/>\n\u0435-mail: <a href=\"mailto:kirichenko47@ukr.net\">kirichenko47@ukr.net<\/a><br \/>\n\u0404\u0424\u0406\u041c\u0415\u041d\u041a\u041e \u0412. \u0412.<br \/>\n\u041d\u0430\u0446\u0456\u043e\u043d\u0430\u043b\u044c\u043d\u0438\u0439 \u0430\u0432\u0456\u0430\u0446\u0456\u0439\u043d\u0438\u0439 \u0443\u043d\u0456\u0432\u0435\u0440\u0441\u0438\u0442\u0435\u0442<br \/>\nORCID ID: 0000-0002-4903-6174<br \/>\n\u0435-mail: <a href=\"mailto:e.valerij.ua@gmail.com\">e.valerij.ua@gmail.com<\/a><br \/>\nOLEKSANDRENKO V.P., SVIDERSRKYI\u00a0 V.P., KIRICHENKO L. M.<br \/>\nKhmelnytsky National University<br \/>\nYEFYMENKO V.V.<br \/>\nNational Aviation University<br \/>\n<strong>DOI:<\/strong> <a href=\"https:\/\/www.doi.org\/10.31891\/2307-5732-2021-301-5-45-51\">https:\/\/www.doi.org\/10.31891\/2307-5732-2021-301-5-45-51<\/a><br \/>\n<strong>\u0420\u0435\u0446\u0435\u043d\u0437\u0456\u044f\/Peer review <\/strong>: 14.09.2021\u0440.<br \/>\n<strong>\u041d\u0430\u0434\u0440\u0443\u043a\u043e\u0432\u0430\u043d\u0430\/Printed :<\/strong> 10.10.2021 \u0440.<br \/>\n<strong>\u0410\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u043c\u043e\u0432\u043e\u044e \u043e\u0440\u0438\u0433\u0456\u043d\u0430\u043b\u0443<\/strong><br \/>\n\u041f\u0440\u043e\u0430\u043d\u0430\u043b\u0456\u0437\u043e\u0432\u0430\u043d\u043e \u0448\u043b\u044f\u0445\u0438 \u0440\u0435\u0433\u0443\u043b\u044e\u0432\u0430\u043d\u043d\u044f \u0430\u0434\u0433\u0435\u0437\u0456\u0457 \u0444\u0442\u043e\u0440\u043e\u043f\u043b\u0430\u0441\u0442\u043e\u0432\u0438\u0445 \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u0456\u0432 \u0434\u043e \u043c\u0435\u0442\u0430\u043b\u0435\u0432\u0438\u0445 \u043f\u043e\u0432\u0435\u0440\u0445\u043e\u043d\u044c. \u0414\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u043e \u0432\u043f\u043b\u0438\u0432 \u0441\u043a\u043b\u0430\u0434\u0443 \u0456 \u0442\u0435\u043c\u043f\u0435\u0440\u0430\u0442\u0443\u0440\u043d\u043e-\u0447\u0430\u0441\u043e\u0432\u0438\u0445 \u0443\u043c\u043e\u0432 \u0444\u043e\u0440\u043c\u0443\u0432\u0430\u043d\u043d\u044f \u0491\u0440\u0443\u043d\u0442\u0443\u0432\u0430\u043b\u044c\u043d\u043e\u0433\u043e \u0448\u0430\u0440\u0443 \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f \u043d\u0430 \u0430\u0434\u0433\u0435\u0437\u0456\u0439\u043d\u0443 \u043c\u0456\u0446\u043d\u0456\u0441\u0442\u044c \u043c\u0435\u0442\u0430\u043b\u043e\u043f\u043e\u043b\u0456\u043c\u0435\u0440\u043d\u0438\u0445 \u0437\u2019\u0454\u0434\u043d\u0430\u043d\u044c.\u00a0 \u0414\u0435\u0442\u0430\u043b\u044c\u043d\u043e \u043e\u043f\u0438\u0441\u0430\u043d\u0456 \u0440\u0435\u0436\u0438\u043c\u0438 \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u0447\u043d\u0438\u0445 \u043e\u043f\u0435\u0440\u0430\u0446\u0456\u0439. \u041d\u0430\u0432\u0435\u0434\u0435\u043d\u0456 \u0432\u043b\u0430\u0441\u0442\u0438\u0432\u043e\u0441\u0442\u0456 \u0491\u0440\u0443\u043d\u0442\u0443\u0432\u0430\u043b\u044c\u043d\u043e\u0433\u043e \u0448\u0430\u0440\u0443 \u0444\u0442\u043e\u0440\u043f\u043e\u043b\u0456\u043c\u0435\u0440\u0443 \u0424-30\u041f. \u041e\u043a\u0440\u0435\u0441\u043b\u0435\u043d\u043e \u043e\u0441\u043e\u0431\u043b\u0438\u0432\u043e\u0441\u0442\u0456 \u0444\u043e\u0440\u043c\u0443\u0432\u0430\u043d\u043d\u044f \u0491\u0440\u0443\u043d\u0442\u0443\u0432\u0430\u043b\u044c\u043d\u043e\u0433\u043e \u0448\u0430\u0440\u0443 \u0444\u0442\u043e\u0440\u043e\u043f\u043b\u0430\u0441\u0442\u043e\u0432\u043e\u0433\u043e \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f. \u0420\u043e\u0437\u0440\u043e\u0431\u043b\u0435\u043d\u0430 \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0456\u044f \u043d\u0430\u043d\u0435\u0441\u0435\u043d\u043d\u044f \u0433\u0440\u0443\u043d\u0442\u0443\u0432\u0430\u043b\u044c\u043d\u043e\u0433\u043e \u0448\u0430\u0440\u0443 \u0444\u0442\u043e\u0440\u043e\u043f\u043b\u0430\u0441\u0442\u043e\u0432\u043e\u0433\u043e \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u044f \u0435\u043b\u0435\u043a\u0442\u0440\u043e\u043e\u0441\u0430\u0434\u0436\u0435\u043d\u043d\u044f\u043c \u043d\u0430 \u043c\u0435\u0442\u0430\u043b\u0435\u0432\u0456 \u043f\u043e\u0432\u0435\u0440\u0445\u043d\u0456. \u0414\u0430\u043d\u0456 \u0440\u0435\u043a\u043e\u043c\u0435\u043d\u0434\u0430\u0446\u0456\u0457 \u0437 \u0432\u0438\u043a\u043e\u0440\u0438\u0441\u0442\u0430\u043d\u043d\u044f \u0440\u0435\u0437\u0443\u043b\u044c\u0442\u0430\u0442\u0456\u0432 \u0432\u0438\u043a\u043e\u043d\u0430\u043d\u0438\u0445 \u0434\u043e\u0441\u043b\u0456\u0434\u0436\u0435\u043d\u044c \u0434\u043b\u044f \u043e\u0442\u0440\u0438\u043c\u0430\u043d\u043d\u044f \u0444\u0442\u043e\u0440\u043e\u043f\u043b\u0430\u0441\u0442\u043e\u0432\u0438\u0445 \u043f\u043e\u043a\u0440\u0438\u0442\u0442\u0456\u0432 \u0437 \u0432\u0438\u0441\u043e\u043a\u043e\u044e \u0430\u0434\u0433\u0435\u0437\u0456\u0454\u044e \u0434\u043e \u043c\u0435\u0442\u0430\u043b\u0435\u0432\u0438\u0445 \u043f\u043e\u0432\u0435\u0440\u0445\u043e\u043d\u044c.<br \/>\n<strong>Key words:\u00a0<\/strong> adhesion, fluoroplastic coatings, strength, composition, technological factors, metal surface.<\/p>\n<p style=\"text-align: center;\"><strong>\u00a0<\/strong><strong>\u0420\u043e\u0437\u0448\u0438\u0440\u0435\u043d\u0430 \u0430\u043d\u043e\u0442\u0430\u0446\u0456\u044f \u0430\u043d\u0433\u043b\u0456\u0439\u0441\u044c\u043a\u043e\u044e \u043c\u043e\u0432\u043e\u044e<\/strong><\/p>\n<p>The ways of regulating adhesion of fluoroplastic coatings to metal surfaces are analyzed. It has been established that polymer and metal modification is necessary to increase the adhesive strength and resistance of fluoroplastic coatings. The relative impact of the nature of the metal on the strength of adhesive compounds of polymer &#8211; metal is less influenced by the nature of the polymer. The strength of metal compounds is significantly affected by the activation of the metal surface by mechanical treatment (grinding etc.). Various methods of oxidation, etching, metal phosphating are recommended to increase the adhesive strength of fluoropolymer coatings. Method of investigation of adhesion and resistance to scratch damage of coatings is given. The influence of composition and temperature-time conditions of the ground layer formation of the coating on adhesive strength of metal-polymeric compounds was investigated. Detailed operation modes are described. The properties of the ground layer of fluoropolymer \u0424-30\u041f are given. The peculiarities of the fluoroplastic coating ground layer formation are outlined. The technology of application of the fluoroplastic coating ground layer on electroplating of metal surfaces has been developed. The coating on the metal surface was done by electrostatic spraying of the ground layer powder at an electric field voltage of 50 kV. The deformation and strength properties of the unstabilized \u0424-30\u041f fluoroplast are found to be quite high, which together with high adhesive strength makes it possible to recommend this polymer as primer. It is also advisable to melt the ground layers in more rigid temeperature-time modes (melting temperature 260<sup>0<\/sup> C, duration &#8211; 2 hours) in order to ensure\u00a0 higher adhesion strength. The adhesive strength of the \u0424-30\u041f fluoroplastic coating can be increased by 10-15% by additional heating at a temperature of 240<sup>0<\/sup> C for two hours. Analysis of the results showed that the resistance of fluoroplastic coatings based on \u0424-30\u041f to damage by scratching with an increase in the graphite content of C-1 from 15% to 25% increases by a factor of 2.11, and inserting to coating with 25 mas.% of C-1 graphite additional 3 mas. % of the aerosil-based amino-ergoholozenese &#8211; 3.16 times. The additional termoprocessing of these coatings increases the resistance to damage by scratching by 30 per cent. Recommendations on the use of research results for obtaining fluoroplastic coatings with high-adhesion to metal surfaces are given.<br \/>\n<strong>Key words:\u00a0<\/strong> adhesion, fluoroplastic coatings, strength, composition, technological factors, metal surface.<\/p>\n<p style=\"text-align: center;\"><strong>References<\/strong><\/p>\n<ol>\n<li>Sina Ebnesajjad. Fluoroplastics Volume 1: Non-Melt Processible Fluoropolymers \/ Sina Ebnesajjad. \u2013The Definitive User&#8217;s Guide and Data Book. \u2013 Second Edition . \u2013 2015. \u2013 698<\/li>\n<li>Sina Ebnesajjad. Fluoroplastics Volume 2: Melt Processible Fluoropolymers \/ Sina Ebnesajjad.\u2013 The Definitive User&#8217;s Guide and Data Book.\u2013 Second Edition . \u2013 2016. \u2013 745 p.<\/li>\n<li>Ftoroplastovye zashhitnye pokrytija [Elektronnij resurs]. \u2013 Rezhim dostupu: http: \/\/ plastpolymer.org\/pokr.htm<\/li>\n<li>\u2116 2439100S2 Rossijskaja federacija MPK C09D 27\/12 (2006.01), V0505\/083. Antiprigarnoe poverhnostnoe pokrytie \/ Vich Majkl. Dzh. (US), Hajakava Osamu (Jp), Adams Dzherom T. (US), patentoobladatel&#8217;: Rossijskaja federacija: E. I. Djupon de Nemur Jend kompani,\u00a0 zajavleno\u00a0 05.10.2010, opubl. 10.01.2012, Bjul. \u2116 28.\u00a0\u00a0 \u2013 18 p.<\/li>\n<li>\u2116 2464107 Rossijskaja federacija MPK C09D 27\/12 (2006.01), V05D5\/08. Sposob naesenija ftorpolimernogo poroshkovogo pokrytija v kachestve gruntovochnogo sloja i verhnego pokryvnogo sloja \/ HENNESSI Krejg King (US) patentoobladatel&#8217;: Rossijskaja federacija: E. I. Djupon de Nemur Jend kompani, zajavleno\u00a0 05.09.2012, opubl. 10.03.2013, Bjul. \u2116 23.\u00a0\u00a0 \u2013 14 p.<\/li>\n<li>\u2116 2490371S1 Rossijskaja federacija MPK C23S 24\/08(2006.01), V32V 15\/04 (2006.01), B22F 7\/04 (2006.01). Sposob poluchenija ftoroplastovogo aniadgezionnogo pokrytija na metallicheskih poverhnostjah \/ Kornopol&#8217;cev V. N., Mognonov D. M., Ajurova O. Zh., Burdjukovskij V. F., Hohloev V. Ch. Zajaviteli i patentoobladateli: Federal&#8217;noe gosudarstvennoe bjudzhetnoe uchrezhdenie nauki Bajkal&#8217;skij institut prirodoispol&#8217;zovanija Sibirskogo otdelenija Rossijskoj akademii nauk (BIP SO RAN), Obshhestvo s ogranichennoj otvetstvennostju \u00abMaloe innovacionnoe predprijatie \u00abMEGARESURS\u00bb (OOO \u00abMIP\u00bb \u00abMEGARESURS\u00bb) zajavka \u2116 2012115977\/02, 19.04.2012, opubl. 10.08.2013, Bjul. \u2116 23.\u00a0 \u2013 7 p.<\/li>\n<li>Suhareva L. A. Ftorlonovye pokrytija: osnovnye svojstva i sposoby ih modifikacii \/ L. A.Suhareva, V. Komarov, E. V. Bakirova \/\/ Sovremennye LKM svojstva i oblasti primenenija. \u2013 Moskovskij gosudarstvennyj universitet prikladnoj biotehnologii, 2020. \u2013 \u2116 9 \u2013\u00a0 P. 64-67. \u2013 Rezhim dostupa: http:\/\/plastpolymer.org\/polgn.htm<\/li>\n<li>Tekhnolohichni protsesy pidhotovky poverkhon&#8217; [Elektronnyj resurs]. \u2013 Svoie dilo. \u2013 2014. \u2013 26.02. \u2013 Rezhym dostupu : https:\/\/proizvodim.com\/texnologichni-procesi-pidgotovki-poverxon.html<\/li>\n<li>Zashhitnye pokrytija iz poroshkov ftorpolimerov \/ [Mulin Ju.A., Kolesnichenko V. V., Ermakova L. P. i dr.]. \u2013 L.: LDNTP, 1985. \u2013 24 p .<\/li>\n<li>Mashinostroitel&#8217;nye ftorkompozity : struktura, tehnologija, primenenie: monografija \/ S.V. Avdejchik, [i dr.] ; pod nauch. red. V. A. Struka. \u2013 Grodno : GrGU im. Janki Kupaly. \u2013 2012.\u2013 339 p.<\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[58],"tags":[],"_links":{"self":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/9885"}],"collection":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=9885"}],"version-history":[{"count":7,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/9885\/revisions"}],"predecessor-version":[{"id":11089,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=\/wp\/v2\/posts\/9885\/revisions\/11089"}],"wp:attachment":[{"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=9885"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=9885"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/journals.khnu.km.ua\/vestnik\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=9885"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}