Надіслати статтю
вул. Інститутська 11, м. Хмельницький, 29016

АКТУАЛЬНІ ПИТАННЯ МОНІТОРИНГУ ВМІСТУ ХЛОРИТІВ ТА ХЛОРАТІВ У ПИТНІЙ ВОДІ  ПІСЛЯ ЗНЕЗАРАЖУВАННЯ ОКИСНЮВАЧАМИ
CURRENT ISSUES OF MONITORING THE CHLORITE AND CHLORITE CONTENT IN DRINKING WATER AFTER OXIDATION DISINFECTION

Сторінки: 7-10. Номер: №4, 2021 (299)
Автори:
А.В. МОКІЄНКО
Одеський національний медичний університет
ORCID ID: 0000-0002-4491-001X
e-mail: mokienkoav56@gmail.com
Л.М. СПАСЬОНОВА
Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського»
e-mail: lar_spas@yahoo.com
О. Ю. БОНДАРЧУК
Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського»
e-mail:     Bondarchukau@gmail.com
A.V. MOKIENKO
Odessa National Medical University
ORCID ID: 0000-0002-4491-001X
e-mail: mokienkoav56@gmail.com
L.M. SPASIONOVA
National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”
ORCID ID: 0000-0002-7562-7241
e-mail: lar_spas@yahoo.com
Yu. BONDARCHUK
National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”
ORCID ID: –
e-mail: Bondarchukau@gmail.com
DOI: https://www.doi.org/10.31891/2307-5732-2021-299-4-7-10
Рецензія/Peer review : 08.08.2021 р.
Надрукована/Printed : 26.08.2021 р.

Анотація мовою оригіналу

В роботі наведено результати узагальнення даних щодо утворення хлоритів та хлоратів у воді внаслідок знезаражування окиснювачами та представлено напрямки досліджень щодо розробки  технологічних засад з мінімізації вмісту цих побічних продуктів у питній воді.
Ключові слова: питна вода, знезаражування, окиснювачі, хлорити, хлорати.

Розширена анотація англійською мовою

The use of oxidants (chlorine, chlorine dioxide and ozone) is a priority way of safe water supply. However, their use involves control of the formation, determination and normalization of chlorites and chlorates as by-products of disinfection. The aim of the work was to characterize the topical issues of monitoring the content of chlorites and chlorates in drinking water after disinfection with oxidants. Research methods included bibliometric and analytical. The results are as follows. The analysis of foreign and domestic normative documents testifies to the need to harmonize the current DSanPiN 2.2.4-171-10 “Hygienic requirements for drinking water suitable for human consumption” regarding the standardization of chlorites and chlorates in accordance with international requirements. It should be noted that these values, namely the normative values ​​for chlorites and chlorates at the level of 0.7 and 0.7 mg / l, respectively, were included in the latest version of the above-mentioned normative document DSanPiN 2.2.4-171-20. An analysis of the experience gained in Europe (European federation of national associations of water services) shows that the main source of chlorite and chlorate formation is not chlorine dioxide, as previously thought, but sodium hypochlorite. According to the WHO, chlorate is a typical by-product of disinfection in the treatment of water with oxidants (sodium hypochlorite, chloramines, chlorine dioxide, ozone). Currently, research on the development of technological principles for minimizing the content of chlorites and chlorates as by-products of water disinfection by oxidants in Ukraine has not been conducted. The above necessitates the implementation of the following tasks: generalization of research results of chlorite content in drinking water from centralized drinking water supply systems, where chlorine dioxide is used; development, testing and implementation of the method of determination of chlorates in drinking water; determination of the content of chlorites and chlorates in the finished sodium hypochlorite, which is supplied to water utilities, depending on the shelf life; monitoring the content of chlorites and chlorates in drinking water of settlements where sodium hypochlorite is used in the process of water treatment; determination of chlorate content in chlorinated tap water after its treatment with ozone; substantiation of optimal modes of water treatment with oxidants to minimize the content of chlorites and chlorates in drinking water from the water distribution network; development of technological principles for minimizing the content of chlorites and chlorates in drinking water after disinfection with oxidants.
Key words: drinking water, disinfection, oxidizers, chlorites, chlorates.

References

  1. Prokopov V. O. Pitna voda Ukraїni: mediko-ekologіchnі ta sanіtarno-gіgієnіchnі aspekti / za red. A. M. Serdjuka. Kiїv : VSV «Medicina» 2016. 400 s.
  2. Mokienko A.V., Petrenko N.F., Gozhenko A.I. Obezzarazhivanie vody. Gigienicheskie i mediko-jekologicheskie aspekty. T. 1. Hlor i ego soedinenija. TJeS, 2011. 484 s.
  3. Mokienko A.V., Petrenko N.F., Gozhenko A.I. Obezzarazhivanie vody. Gigienicheskie i mediko-jekologicheskie aspekty. T. 2. Dioksid hlora. Odessa. TJeS, 2012. 604 s.
  4. Mokienko A.V., Petrenko N.F., Gozhenko A.I. Obezzarazhivanie vody. Gigienicheskie i mediko-jekologicheskie aspekty. T. 3. Ozon. Fenіks. 2017. 322 s.
  5. Mokienko A.V. Obezzarazhivanie vody. Gigienicheskie i mediko – jekologicheskie aspekty. Tom 4. Ul’trafioletovoe obluchenie i kombinirovannye metody. Odessa. Fenіks. 2020. 378 s.
  6. Mokienko A.V. Dioksid hlora: primenenie v tehnologijah vodopodgotovki 2-e izd. pererab i dop. Odessa : «Fenіks», 2021. 336 s.
  7. Pro zatverdzhennja Derzhavnih sanіtarnih norm ta pravil “Gіgієnіchnі vimogi do vodi pitnoї, priznachenoї dlja spozhivannja ljudinoju” 2.2.4-171–10. Nakaz Mіnіsterstva ohoroni zdorov’ja Ukraїni vіd 12 travnja 2010 roku N 400. Zareєstrovano v Mіnіsterstvі justicії Ukraїni 1 lipnja 2010 r. za N 452/17747. Rezhim dostupu: https://zakon.rada.gov.ua/laws/show/z0452-10#Text
  8. Guidelines for drinking water quality: fourth edition incorporating the first addendum. World Health Organisation. Licence CC BY-NC-SA 3.0 IGO 2017. 631 p.
  9. Directive (EU) 2020/2184 of the European parliament and of the council of 16 December 2020 on the quality of water intended for human consumption (recast). Rezhim dostupu: https://eur-lex.europa.eu/legal-content/EN/TXT/PDF/?uri=CELEX:32020L2184&from=ES.
  10. Siddiqui M. S. Chlorine-ozone interactions: Formation of chlorate M. S. Siddiqui // Water Research. – 1996. – V. 30, N 9.  – P. 2160  – 2170.
  11. Asami M. Bromate, chlorate, chlorite and perchlorate in sodium hypochlorite solution used in water supply / M. Asami, K. Kosaka, S. Kunikane // Journal of Water Supply: Research and Technology—AQUA. – 2009. – V. 58, N 2. – P. 107 – 115
  12. WHO Chlorite and chlorate in drinking-water. Background document for preparation of WHO Guidelines for drinking-water quality. Geneva, World Health Organization (WHO/SDE/WSH/03.04/86) . – 2003.
  13. EurEau (European federation of national associations of water services). 2018. Rezhim dostupu: https://www.eureau.org/resources/position-papers/3012-drinking-water-directive-plenary-vote-eureau-explanatory-memorandum-1/file
  14. Mokienko A. V. Jekologo-gigienicheskie osnovy bezopasnosti vody, obezzarazhennoj dioksidom hlora. Dis. … d. med. n.:  02.01  GU«Institut gigieny i medicinskoj jekologii  im. A.N. Marzeeva AMN Ukrainy». K.. 2009. 348 s.
  15. Fomin G.S., Fomina O.N. Pit’evaja i mineral’naja voda. Trebovanija mirovyh i evropejskih standartov k kachestvu i bezopasnosti. Moskva:“Protektor”. 320 s.
  16. Subchronic toxicity of sodium chlorite in the rat. M. Harrington et al. Jour. Amer. Coll. Toxicol. 1995. V 14, N 1. P. 21 – 28.
  17. Aieta E.M., Roberts P.V., Hernandez M. Determination of Chlorine Dioxide, Chlorine, Chlorite and Chlorate in Water. J.AWWA. 1984. V.76, № 7. P. 64 – 74.

Post Author: npetliaks

Translate